1,2-Bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]-4,5-dinitrobenzene

Base Information

• Chemical Name: 1,2-Bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]-4,5-dinitrobenzene
• CAS No.: 165254-21-7
• Molecular Formula: C20H32N2O12
• Molecular Weight: 492.48
• UNII: YB9V0MDTEJ
• DSSTox Substance ID: DTXSID10572506
• Wikidata: Q82460869
• Mol file: 165254-21-7.mol

Synonyms:165254-21-7;YB9V0MDTEJ;UNII-YB9V0MDTEJ;1,2-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]-4,5-dinitrobenzene;1,2-Bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-4,5-dinitrobenzene;Benzene, 1,2-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-4,5-dinitro-;Benzene, 1,2-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]-4,5-dinitro-;1,2-BIS{2-[2-(2-METHOXYETHOXY)ETHOXY]ETHOXY}-4,5-DINITROBENZENE;SCHEMBL4111905;DTXSID10572506;RLKFEUVQBGLTFI-UHFFFAOYSA-N;1,2-bis[2-[2-(2-methoxyethoxy) ethoxy]ethoxy]-4,5-dinitrobenzene

Chemical Property of 1,2-Bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]-4,5-dinitrobenzene

Chemical Property:

• PSA: 165.48000
• LogP: 2.66620
• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 20
• Exact Mass: 492.19552446
• Heavy Atom Count: 34
• Complexity: 485

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCCOCCOCCOC1=C(C=C(C(=C1)[N+](=O)[O-])[N+](=O)[O-])OCCOCCOCCOC

Technology Process of 1,2-Bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]-4,5-dinitrobenzene

There total 6 articles about 1,2-Bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]-4,5-dinitrobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,2-bis[2-[2-(2-methoxyethoxy)-ethoxy]ethoxy]-benzene (57721-95-6) → 1,2-bis[2-[2-(2-methoxyethoxy]ethoxy]ethoxy]-4,5-dinitrobenzene (165254-21-7)

Guidance literature:

With nitric acid; In acetic acid; at 0 - 20 ℃;

DOI:10.1246/cl.2010.226

Reference yield: 22.0%

triethylene glucol monomethyl ether (112-35-6,95507-80-5) + 1,2-dinitro-4,5-difluorobenzene (85686-97-1) → 1,2-bis[2-[2-(2-methoxyethoxy]ethoxy]ethoxy]-4,5-dinitrobenzene (165254-21-7)

Guidance literature:

triethylene glucol monomethyl ether; With sodium hydride; In 1,2-dimethoxyethane; mineral oil; at 20 ℃; for 1h; Inert atmosphere;

1,2-dinitro-4,5-difluorobenzene; In 1,2-dimethoxyethane; mineral oil; at 20 ℃; Inert atmosphere;

DOI:10.1021/ja308055s

Reference yield:

1,2-diamino-4,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]benzene (165254-22-8) + pyrographite (7440-44-0) → 1,2-bis[2-[2-(2-methoxyethoxy]ethoxy]ethoxy]-4,5-dinitrobenzene (165254-21-7)

Guidance literature:

With hydrogenchloride; In methanol;

upstream raw materials:

1,2-diamino-4,5-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]benzene

pyrographite

1,2-bis[2-[2-(2-methoxyethoxy)-ethoxy]ethoxy]-benzene

triethylene glucol monomethyl ether