tetracarbonyl(η3-1-phenyl-3-hexen-5-yl)manganese

Base Information

• Chemical Name: tetracarbonyl(η3-1-phenyl-3-hexen-5-yl)manganese
• CAS No.: 85040-31-9
• Molecular Formula: C₁₆H₁₅MnO₄
• Molecular Weight: 326.231
• Mol file: 85040-31-9.mol

Synonyms:

Chemical Property of tetracarbonyl(η3-1-phenyl-3-hexen-5-yl)manganese

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetracarbonyl(η3-1-phenyl-3-hexen-5-yl)manganese

There total 1 articles about tetracarbonyl(η3-1-phenyl-3-hexen-5-yl)manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-methylbuta-1,3-diene (2004-70-8,17410-45-6,25212-15-1,64940-84-7) + benzylpentacarbonylmanganese → η3-(CH3CHCHCHCH3)Mn(CO)4 + tetracarbonyl(η3-1-phenyl-3-hexen-5-yl)manganese (85040-31-9)

Guidance literature:

In hexane; Irradiation (UV/VIS); under N2, educts in n-hexane irradiated with UV lamp (TQ 150, Original Hanau Heraeus Quarzlampen Gmbh) at 253 K for 60 min, filtered, heated under reflux for 30 min; evapd.;

DOI:10.1016/S0022-328X(00)98506-1

Reference yield:

benzylpentacarbonylmanganese + η3-(CH3CHCHCHCH3)Mn(CO)4 + tetracarbonyl(η3-1-phenyl-3-hexen-5-yl)manganese (85040-31-9) + trimethylphosphane (594-09-2) → fac-tricarbonyl-η3-((EE)-2-penten-4-yl)-trimethylphosphine-manganese (85040-49-9) + fac-tricarbonyl-η3-((EE)-1-phenyl-1-hexen-3-yl)-trimethylphosphine-manganese

Guidance literature:

In hexane; under N2, Mn complexes dissolved in hexane, treated with PMe3, stirred at room temp. for 3-4 h / further products; evapd., taken in pentane, filtered through Al2O3, concd., sepd. by HPLCSiO2, hexane/CH2Cl2), evapd., taken in pentane, filtered, concd., crystd. by cooling to 195 K, mother liquor decanted, dried in high vac. for 3h; elem. anal.;

DOI:10.1016/S0022-328X(00)98506-1

Reference yield:

benzylpentacarbonylmanganese + η3-(CH3CHCHCHCH3)Mn(CO)4 + trimethylarsine (593-88-4) + tetracarbonyl(η3-1-phenyl-3-hexen-5-yl)manganese (85040-31-9) → fac-tricarbonyl-η3-((EE)-2-penten-4-yl)-trimethylarsine-manganese (85040-50-2) + tricarbonyl-η3-((EE)-1-phenyl-1-hexen-3-yl)-trimethylarsine-manganese + cis-benzyltetracarbonyl-trimethylarsine-manganese (85040-33-1) + tricarbonyl-η3-((EE)-1-phenyl-3-hexen-5-yl)-trimethylarsine-manganese

Guidance literature:

In hexane; under N2, Mn complexes dissolved in hexane, treated with AsMe3, stirredat room temp. for 10 d; evapd., taken in pentane, filtered through Al2O3, concd., sepd. by HPLCSiO2, hexane/CH2Cl2), evapd., taken in pentane, filtered, concd., crystd. by cooling to 195 K, mother liquor decanted, dried in high vac. for 3h; elem. anal.;

DOI:10.1016/S0022-328X(00)98506-1

upstream raw materials:

1-methylbuta-1,3-diene

Downstream raw materials:

fac-tricarbonyl-η3-((EE)-2-penten-4-yl)-trimethylarsine-manganese

cis-benzyltetracarbonyl-trimethylarsine-manganese

fac-tricarbonyl-η3-((EE)-2-penten-4-yl)-trimethylphosphine-manganese

cis-benzyl-tetracarbonyl-trimethylphosphine-manganese