Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)CH₂CH₂)⁽¹⁺⁾*SO₃CF₃^(1-)=(Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)C₂H₄))SO₃CF₃

Base Information

• Chemical Name: Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)CH₂CH₂)⁽¹⁺⁾*SO₃CF₃^(1-)=(Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)C₂H₄))SO₃CF₃
• CAS No.: 913843-26-2
• Molecular Formula: CF₃O₃S*C₃₈H₃₃F₆OP₂Pd
• Molecular Weight: 937.108
• Mol file: 913843-26-2.mol

Synonyms:

Chemical Property of Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)CH₂CH₂)⁽¹⁺⁾*SO₃CF₃^(1-)=(Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)C₂H₄))SO₃CF₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)CH₂CH₂)⁽¹⁺⁾*SO₃CF₃^(1-)=(Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)C₂H₄))SO₃CF₃

There total 1 articles about Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)CH₂CH₂)⁽¹⁺⁾*SO₃CF₃^(1-)=(Pd((C₆H₅)2PCH₂C₆H₄CH₂P(C₆H₄CF₃)2)(OC(CH₃)C₂H₄))SO₃CF₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethene (74-85-1) + [Pd(NCCH3)(CH3)(1-(diphenylphosphinomethyl)-2-[bis(3-trifluoromethylphenyl)phosphinomethyl]benzene)](trifluoromethane sulfonate) (917496-93-6,913729-25-6,917496-95-8) + carbon monoxide (201230-82-2) → Pd((C6H5)2PCH2C6H4CH2P(C6H4CF3)2)(OC(CH3)CH2CH2)(1+)*SO3CF3(1-)=(Pd((C6H5)2PCH2C6H4CH2P(C6H4CF3)2)(OC(CH3)C2H4))SO3CF3 (913843-26-2) + Pd((C6H5)2PCH2C6H4CH2P(C6H4CF3)2)(OC(CH3)CH2CH2)(1+)*SO3CF3(1-)=(Pd((C6H5)2PCH2C6H4CH2P(C6H4CF3)2)(OC(CH3)C2H4))SO3CF3 (913728-99-1)

Guidance literature:

In chloroform-d1; CO bubbled through CDCl3 soln. of Pd complex at -60°C for 5-10 min; warmed to -20°C; ethene (25-28 equiv.) added; not isolated; detd. by (1)H and (31)P NMR spectra; mixt. of two isomer (1:1) obtained;

DOI:10.1016/j.jorganchem.2006.06.029

upstream raw materials:

ethene

[Pd(NCCH₃)(CH₃)(1-(diphenylphosphinomethyl)-2-[bis(3-trifluoromethylphenyl)phosphinomethyl]benzene)](trifluoromethane sulfonate)

carbon monoxide