Phenyl(triphenylmethyl) sulfide

Base Information

• Chemical Name: Phenyl(triphenylmethyl) sulfide
• CAS No.: 16928-73-7
• Molecular Formula: C25H20S
• Molecular Weight: 352.5
• Hs Code.: 2930909090
• Mol file: 16928-73-7.mol

Synonyms:Phenylmercapto-triphenyl-methan;triphenylmethyl phenyl sulfide;phenyl triphenylmethyl sulfide;Phenyl-trityl-sulfid;Sulfide,phenyl trityl;phenyltriphenylmethylsufide;phenyl-trityl sulfide;Benzene,1,1',1''-[(phenylthio)methylidyne]tris;

Chemical Property of Phenyl(triphenylmethyl) sulfide

Chemical Property:

• PSA: 25.30000
• LogP: 6.77080

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phenyl(triphenylmethyl) sulfide

There total 22 articles about Phenyl(triphenylmethyl) sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

diphenyldisulfane (882-33-7) + potassium triphenyl acetate → triphenylmethyl phenyl sulfide (16928-73-7)

Guidance literature:

In dimethyl sulfoxide; at 80 ℃; for 24h; Inert atmosphere;

DOI:10.1039/d1ra00063b

Reference yield: 94.0%

C30H41NiP3S + trityl chloride (76-83-5) → triphenylmethyl phenyl sulfide (16928-73-7) + C24H36ClNiP3

Guidance literature:

In benzene-d6; benzene; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.6b00253

Reference yield: 91.0%

C31H41NiOP3S + trityl chloride (76-83-5) → triphenylmethyl phenyl sulfide (16928-73-7) + C24H36ClNiP3

Guidance literature:

In benzene; at 60 ℃; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.6b00253

upstream raw materials:

diethyl ether

diphenyl sulfide

triphenylmethyl sodium

sodium thiophenolate

Downstream raw materials:

triphenylmethyl alcohol

triphenylmethyl potassium

N-tritylacetamide

diphenyldisulfane

Refernces

• 1、 Xing, Wei-Long,Liu, De-Guang,Fu, Ming-Chen. "Transition-metal-free decarboxylative thiolation of stable aliphatic carboxylates". . p. 4593 - 4597. Retrieved 2021/02/03.
• 2、 Oh, Seohee,Lee, Yunho. "Reversible Intramolecular P-S Bond Formation Coupled with a Ni(0)/Ni(II) Redox Process". . p. 1586 - 1592. Retrieved 2016/07/06.