Butanal, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(4-methylphenyl)sulfonyl]oxy]-, (3S)-

Base Information Edit

Chemical Name:Butanal, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(4-methylphenyl)sulfonyl]oxy]-, (3S)-
CAS No.:169522-70-7
Molecular Formula:C17H28O5SSi
Molecular Weight:372.558
Hs Code.:
Mol file:169522-70-7.mol

Synonyms:

Suppliers and Price of Butanal, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(4-methylphenyl)sulfonyl]oxy]-, (3S)-

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Butanal, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(4-methylphenyl)sulfonyl]oxy]-, (3S)- Edit

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Butanal, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(4-methylphenyl)sulfonyl]oxy]-, (3S)-

There total 2 articles about Butanal, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-4-[[(4-methylphenyl)sulfonyl]oxy]-, (3S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 169522-69-4
Methyl (S)-3-<(tert-butyldimethylsilyl)oxy>-4-(tosyloxy)butanoate

: 169522-70-7
(S)-3-<(tert-butyldimethylsilyl)oxy>-4-(tosyloxy)butanal

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; toluene; at -90 ℃; for 0.5h;
DOI:10.1021/jo00127a045

Reference yield:

: 130403-84-8
methyl (3S)-3-hydroxy-4-{[(4-methylphenyl)sulfonyl]oxy}butanoate

: 169522-70-7
(S)-3-<(tert-butyldimethylsilyl)oxy>-4-(tosyloxy)butanal

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / imidazole / dimethylformamide / 12 h / Ambient temperature

2: 78 percent / DIBAL / CH₂Cl₂; toluene / 0.5 h / -90 °C

With 1H-imidazole; diisobutylaluminium hydride; In dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo00127a045