tripropylsilyl acetate

Base Information

• Chemical Name: tripropylsilyl acetate
• CAS No.: 17315-26-3
• Molecular Formula: C11H24O2Si
• Molecular Weight: 216.396
• Mol file: 17315-26-3.mol

Synonyms:

Chemical Property of tripropylsilyl acetate

Chemical Property:

• Vapor Pressure: 0.0832mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tripropylsilyl acetate

There total 5 articles about tripropylsilyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

tripropylsilane (998-29-8) + acetic acid (64-19-7,77671-22-8) → tri-n-propylsilyl acetate (17315-26-3)

Guidance literature:

With triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃; for 12h;

DOI:10.1080/00397910701465669

Reference yield:

chlorotripropylsilane (995-25-5) → tri-n-propylsilyl acetate (17315-26-3)

Guidance literature:

With KCH₃COO; In Petroleum ether;

Reference yield:

tripropylsilane (998-29-8) → tri-n-propylsilyl acetate (17315-26-3)

Guidance literature:

Multi-step reaction with 2 steps

1: Br₂

With Br₂;

upstream raw materials:

tripropylbromosilane

silver(I) acetate

tripropylsilane

acetic acid

Downstream raw materials:

tripropylsilanol

hexapropyl-disiloxane

Refernces

• 1、 Liu, Guo-Bin,Zhao, Hong-Yun,Thiemann, Thies. "Two new catalysts for the dehydrogenative coupling reaction of carboxylic acids with silanes - Convenient methods for an atom-economical preparation of silyl esters". . p. 2717 - 2727. Retrieved 2008/02/12.
• 2、 Liu, Guo-Bin. "Preparation of silyl esters by ZnCl2-catalyzed dehydrogenative cross-coupling of carboxylic acids and silanes". . p. 1431 - 1433. Retrieved 2007/10/03.