Bis(p-chlorobenzyl) sulphide

Base Information

• Chemical Name: Bis(p-chlorobenzyl) sulphide
• CAS No.: 23566-23-6
• Molecular Formula: C14H12 Cl2 S
• Molecular Weight: 283.221
• Hs Code.: 2930909090
• European Community (EC) Number: 245-743-3
• NSC Number: 409397
• UNII: X9ALX5G95X
• DSSTox Substance ID: DTXSID00178192
• Nikkaji Number: J31.934A
• Wikidata: Q83048571
• Mol file: 23566-23-6.mol

Synonyms:Bis(p-chlorobenzyl) sulphide;23566-23-6;EINECS 245-743-3;NSC-409397;Benzene, 1,1'-[thiobis(methylene)]bis[4-chloro-;Bis(4-chlorobenzyl) sulfide;Benzene, 1,1'-(thiobis(methylene))bis(4-chloro-;1-chloro-4-[(4-chlorophenyl)methylsulfanylmethyl]benzene;NSC409397;Bis-(p-chlorobenzyl)sulfide;X9ALX5G95X;di-(4-chlorobenzyl) sulfide;C14H12Cl2S;Bis(4-chlorobenzyl)monosulfide;Bis(4-chlorobenzyl) sulfide #;SCHEMBL3674399;Sulfane, bis(4-chlorobenzyl)-;C14-H12-Cl2-S;DTXSID00178192;C(SCc1ccc(Cl)cc1)c2ccc(Cl)cc2;NSC 409397;1,1'-[thiodi(methylene)]bis(4-chlorobenzene);1,1'-[Thiobis(methylene)]bis[4-chlorobenzene]

Chemical Property of Bis(p-chlorobenzyl) sulphide

Chemical Property:

• Vapor Pressure: 1.29E-05mmHg at 25°C
• Boiling Point: 379.3°C at 760 mmHg
• Flash Point: 171°C
• PSA: 25.30000
• Density: 1.282g/cm³
• LogP: 5.42680
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 282.0036769
• Heavy Atom Count: 17
• Complexity: 184

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC(=CC=C1CSCC2=CC=C(C=C2)Cl)Cl

Technology Process of Bis(p-chlorobenzyl) sulphide

There total 15 articles about Bis(p-chlorobenzyl) sulphide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-chlorobenzaldehyde (104-88-1) → 1,1’-[thiobis(methylene)]bis[4-chlorobenzene] (23566-23-6)

Guidance literature:

With sulfur; indium (III) iodide; 1,1,3,3-Tetramethyldisiloxane; In dichloromethane; at 80 ℃; for 2h; Inert atmosphere; Sealed tube;

DOI:10.1002/ejoc.201403567

Reference yield: 93.0%

bis-(4-chloro-benzyl)-sulfoxide (74002-20-3) → 1,1’-[thiobis(methylene)]bis[4-chlorobenzene] (23566-23-6)

Guidance literature:

With 1,3,5-trichloro-2,4,6-triazine; In various solvent(s); for 1h; Heating;

DOI:10.1055/s-1980-28973

Reference yield: 87.0%

para-chlorobenzoic acid (74-11-3) → 1,1’-[thiobis(methylene)]bis[4-chlorobenzene] (23566-23-6)

Guidance literature:

With sulfur; indium (III) iodide; 1,1,3,3-Tetramethyldisiloxane; In dichloromethane; at 80 ℃; for 20h; Inert atmosphere; Sealed tube;

DOI:10.1002/ejoc.201403567

upstream raw materials:

1-Chloro-4-(chloromethyl)benzene

4-chlorobenzyl bromide

bis-(4-chloro-benzyl)-sulfoxide

(4-chlorophenyl)methanethiol

Downstream raw materials:

bis-(4-chloro-benzyl)-sulfoxide

di(4-chlorobenzyl) sulfone

4-chlorobenzaldehyde

di(4-chlorobenzyl)phenylsulfonium tetrafluoroborate