74002-20-3

Basic information

• Product Name: bis-(4-chloro-benzyl)-sulfoxide
• Synonyms: bis-(4-chloro-benzyl)-sulfoxide
• CAS NO: 74002-20-3
• Molecular Weight: 299.221
• Mol File: 74002-20-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: bis-(4-chloro-benzyl)-sulfoxide(CAS DataBase Reference)
• NIST Chemistry Reference: bis-(4-chloro-benzyl)-sulfoxide(74002-20-3)
• EPA Substance Registry System: bis-(4-chloro-benzyl)-sulfoxide(74002-20-3)

Safety Data

• Hazardous Substances Data: 74002-20-3(Hazardous Substances Data)

Upstream product

• 23566-23-6 1,1’-[thiobis(methylene)]bis[4-chlorobenzene] 
• 108-88-3 toluene 
• 67-63-0 isopropyl alcohol 
• 93-59-4 Perbenzoic acid 
• 937-21-3 4-methylperbenzoic acid 

Downstream Products

• 23566-23-6 1,1’-[thiobis(methylene)]bis[4-chlorobenzene] 

Relevant articles and documents

Synthesis and characterization of oxo-vanadium complex anchored onto SBA-15 as a green, novel and reusable nanocatalyst for the oxidation of sulfides and oxidative coupling of thiols

Abstract: The present work describes the synthesis of a new oxo-vanadium complex immobilized on SBA-15 nanostructure as an efficient catalyst for oxidation of sulfides and oxidative coupling of thiols. Characterization of the resultant AMPD@SBA-15 nanostructure was performed by various physico-chemical techniques such as Fourier transform infrared spectroscopy, transmission and scanning electron microscopies, energy-dispersive X-ray spectroscopy, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, thermal gravimetric analysis, and N2 adsorption and desorption. The results of the developed procedure bring several benefits such as the use of commercially available, ecologically benign, operational simplicity, and cheap and chemically inert reagents. It shows good reaction times, practicability and high efficiency, and is easily recovered from the reaction mixture by simple filtration and reused for several consecutive cycles without noticeable change in its catalytic activity. More importantly, high efficiency, simple and an inexpensive procedure, commercially available materials, easy separation, and an eco-friendly procedure are the several advantages of the currently employed heterogeneous catalytic system.

Chiral amination sulfoxide and preparation method thereof (by machine translation)

The invention belongs to the field of organic synthesis, and discloses chiral amination sulfoxide which has the structure of a general formula I. Wherein R is hydrogen or R1 And R2 Each independently selected from one of the following structures: hydrogen, alkyl, alkoxy, ester, trifluoromethyl, trifluoromethoxy, trifluoromethylthio. Halogens, alkynyl groups, alkenyl groups, amino groups, cyano groups, hydroxyl groups, aldehyde groups, carboxyl groups, nitro groups, amide groups, benzene rings, and bonded benzene ring fused rings to naphthalene; R3 Selected from the group consisting of phenyl, optionally substituted phenyl, aryl, heteroaryl, styryl, alkyl, haloalkyl and the like. The method comprises the following steps: forming a complex with a tert-butyl cyclopentadienyl metal iridium complex, forming a complex with the modified chiral proline, and activating C-H bond of enantioselective induced sulfoxide to obtain chiral sulphoxide. The synthetic method disclosed by the invention is high in yield and good in enantioselectivity, and the obtained amidated sulfoxide can be derivatized to obtain a chiral ligand. (by machine translation)

NOVEL ADDUCTS OF SULFIDES AND 4-SUBSTITUTED 1,2,4-TRIAZOLINE-3,5-DIONES ( TAD )- A SIMILARITY OF TAD AND SINGLET OXYGEN ( 1O2 ) -

The 4-substituted 1,2,4-triazoline-3,5-diones( 2 ) afford with sulfides( 1 ) having acidic α-hydrogens the 1,4-disubstituted urazoles( 3 ).Reactivity of the triazoline-dione shows similarity in possible reaction modes with that of singlet oxygen.