[palladium(II)(4-SC₄H₂C(H)=NCy)(O₂CMe)]2

Base Information

• Chemical Name: [palladium(II)(4-SC₄H₂C(H)=NCy)(O₂CMe)]2
• CAS No.: 1015807-60-9
• Molecular Formula: C₂₆H₃₄N₂O₄Pd₂S₂
• Molecular Weight: 715.539
• Mol file: 1015807-60-9.mol

Synonyms:

Chemical Property of [palladium(II)(4-SC₄H₂C(H)=NCy)(O₂CMe)]2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [palladium(II)(4-SC₄H₂C(H)=NCy)(O₂CMe)]2

There total 1 articles about [palladium(II)(4-SC₄H₂C(H)=NCy)(O₂CMe)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

palladium diacetate (3375-31-3) + 3-SC4H3C(H)=NCy (191922-43-7) → [palladium(II)(3-SC4H2C(H)=NCy)(O2CMe)]2 (1015807-58-5) + [palladium(II)(4-SC4H2C(H)=NCy)(O2CMe)]2 (1015807-60-9)

Guidance literature:

In toluene; (Ar); organic ligand and Pd(OAc)2 added to dry toluene; soln. heated at 80°C for 3 h; cooled to room temp.; filtered; solvent removed under vacuum; chromatographed on silica gel column; eluted with CH2Cl2/CH3OH (1%); concd.; recrystallized from CHCl3/hexane; complexes obtained in 1:1 ratio in 73% overall yield; elem. anal.;

DOI:10.1002/zaac.200600371

Reference yield:

[palladium(II)(4-SC4H2C(H)=NCy)(O2CMe)]2 (1015807-60-9) + triphenylphosphine (603-35-0) → [palladium(II)(4-SC4H2C(H)=NCy)(O2CMe)(PPh3)] (1015807-72-3) + [palladium(II)(3-SC4H2C(H)=NCy)(O2CMe)(PPh3)] (1015807-70-1)

Guidance literature:

In dichloromethane; 2 equiv. of PPh3 added to Pd-complex in CH2Cl2; mixt. stirred for 4 h; filtered over celite; solvent eliminated under reduced pressure; recrystallized from CH2Cl2/n-hexane; overall yield: 79%; elem. anal.;

DOI:10.1002/zaac.200600371

Reference yield:

[palladium(II)(3-SC4H2C(H)=NCy)(O2CMe)]2 (1015807-58-5) + [palladium(II)(4-SC4H2C(H)=NCy)(O2CMe)]2 (1015807-60-9) + sodium bromide (7647-15-6) → [palladium(II)(3-SC4H2C(H)=NCy)(Br)]2 (1015807-64-3) + [palladium(II)(4-SC4H2C(H)=NCy)(Br)]2 (1015807-68-7)

Guidance literature:

In water; acetone; aq. NaBr added to acetone soln. of Pd-complexes; stirred at room temp. for 3 h; water added; filtered off; dried in vacuo; overall yield: 72%; elem. anal.;

DOI:10.1002/zaac.200600371

upstream raw materials:

palladium diacetate

3-SC₄H₃C(H)=NCy

Downstream raw materials:

[palladium(II)(3-SC₄H₂C(H)=NCy)(Br)]2

[palladium(II)(4-SC₄H₂C(H)=NCy)(Br)]2

[palladium(II)(4-SC₄H₂C(H)=NCy)(Cl)]2

[palladium(II)(3-SC₄H₂C(H)=NCy)(Cl)]2

Refernces