Silanediamine, N,N'-bis(1,1-dimethylethyl)-1,1-dimethyl-

Base Information

• Chemical Name: Silanediamine, N,N'-bis(1,1-dimethylethyl)-1,1-dimethyl-
• CAS No.: 17940-08-8
• Molecular Formula: C10H26N2Si
• Molecular Weight: 202.415
• European Community (EC) Number: 842-563-2
• DSSTox Substance ID: DTXSID30276397
• Nikkaji Number: J1.187.638B
• Wikidata: Q82006894
• Mol file: 17940-08-8.mol

Synonyms:17940-08-8;Silanediamine, N,N'-bis(1,1-dimethylethyl)-1,1-dimethyl-;SCHEMBL3114467;DTXSID30276397

Chemical Property of Silanediamine, N,N'-bis(1,1-dimethylethyl)-1,1-dimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 202.186525372
• Heavy Atom Count: 13
• Complexity: 145

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)(C)N[Si](C)(C)NC(C)(C)C

Technology Process of Silanediamine, N,N'-bis(1,1-dimethylethyl)-1,1-dimethyl-

There total 10 articles about Silanediamine, N,N'-bis(1,1-dimethylethyl)-1,1-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(CH3)2Si(NC(CH3)3)(NHC(CH3)3)Sn(1+)*Br(1-) + 1,3-di-t-butyl-2,2-dimethyl-1,3,2,4λ2-diazasilastannetidine (54724-62-8) + tert-butylamine (75-64-9) → Sn3(NC(CH3)3)4H3(1+)*Br(1-)*0.5C6H6 + bis(tert-butylamino)dimethylsilane (17940-08-8)

Guidance literature:

In benzene; tert-butylamine was added dropwise to a stirred mixture of Me2Si(N-t-Bu)2Sn and Me2Si(t-BuNH)(N-t-Bu)SnBr in benzene under N2, pptn., soln. was refluxed for 2 h; removal of the volatiles in vacuo, recrystn. of the residue (benzene);

Reference yield: 94.0%

(CH3)2Si(NC(CH3)3)(NHC(CH3)3)Sn(1+)*I(1-) + 1,3-di-t-butyl-2,2-dimethyl-1,3,2,4λ2-diazasilastannetidine (54724-62-8) + tert-butylamine (75-64-9) → Sn3(NC(CH3)3)4H3(1+)*I(1-)*0.5C6H6 + bis(tert-butylamino)dimethylsilane (17940-08-8)

Guidance literature:

In benzene; tert-butylamine was added dropwise to a stirred mixture of Me2Si(N-t-Bu)2Sn and Me2Si(t-BuNH)(N-t-Bu)SnI in benzene under N2, pptn., soln. was refluxed for 2 h; removal of the volatiles in vacuo, recrystn. of the residue (benzene);

Reference yield: 93.0%

2Sn(2+)*2Br(1-)*2NHC(CH3)3(1-)={NHC(CH3)3SnBr}2 + 1,3-di-t-butyl-2,2-dimethyl-1,3,2,4λ2-diazasilastannetidine (54724-62-8) + tert-butylamine (75-64-9) → Sn3(NC(CH3)3)4H3(1+)*Br(1-)*0.5C6H6 + bis(tert-butylamino)dimethylsilane (17940-08-8)

Guidance literature:

In benzene; tert-butylamine was added dropwise to a mixture of Me2Si(N-t-Bu)2Sn and ((t-BuNH)SnBr)2 in benzene under N2, pptn., soln. was refluxed for 2 h; volatiles were removed in vacuo, recrystn. of the residue (benzene), elem. anal.;

upstream raw materials:

1,3-di-t-butyl-2,2-dimethyl-1,3,2,4λ2-diazasilastannetidine

tert-butylamine

1,3-di-tert-butyl-2,2-dimethyl-1,3,2,4-diazasilagermaetidine

cyclohexa-1,3-diene

Downstream raw materials:

GeCl(2,6-iPr₂C₆H₃NC₇H₈P((NtBu)2SiMe₂))

C₂₉H₅₀N₃PSi

1,3-di-tert-butyl-2-fluoro-2-(2,4,6-trimethylanilino)-4,4-dimethyl-1,3-diaza-2,4-disilacyclobutane

1,3-di-tert-butyl-2-fluoro-2-(3,5-dimethylanilino)-4,4-dimethyl-1,3-diaza-2,4-disilacyclobutane