2-(TRIMETHYLSILYL)NAPHTHALENE

Base Information

• Chemical Name: 2-(TRIMETHYLSILYL)NAPHTHALENE
• CAS No.: 18052-85-2
• Molecular Formula: C13H16Si
• Molecular Weight: 200.356
• Mol file: 18052-85-2.mol

Synonyms:Silane,trimethyl-2-naphthyl;Silane,trimethyl-2-naphthalenyl;

Chemical Property of 2-(TRIMETHYLSILYL)NAPHTHALENE

Chemical Property:

• PSA: 0.00000
• LogP: 3.38500

Purity/Quality:

97% ^*data from raw suppliers

2-(TRIMETHYLSILYL)NAPHTHALENE ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(TRIMETHYLSILYL)NAPHTHALENE

There total 22 articles about 2-(TRIMETHYLSILYL)NAPHTHALENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

chloro-trimethyl-silane (75-77-4) + 2-bromonaphthalene (580-13-2) → 2-naphthyltrimethylsilane (18052-85-2)

Guidance literature:

2-bromonaphthalene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

chloro-trimethyl-silane; In tetrahydrofuran; hexane; at -78 - 20 ℃;

DOI:10.1002/chem.201103061

Reference yield: 95.0%

(1-4a,8a-η-2-trimethylsilylnaphthalene)Cr(CO)3 (279688-22-1,105063-52-3,105063-55-6,279688-21-0,279687-72-8,279687-70-6) → 2-naphthyltrimethylsilane (18052-85-2) + chromium(0) hexacarbonyl (199620-14-9,13007-92-6)

Guidance literature:

With carbon monoxide; In hexane; hexane soln. of the Cr-complex was stirred for 48 h at 60°C under an atmosphere of CO (4 atm); concd., cooled to -78°C, decanted from the pptd. Cr(CO)6, evapn. of the soln. yielded 2-Me3Si-naphthalene (identified by its (1)H NMR spectrum);

Reference yield: 94.0%

naphthalen-2-yl(trimethylsilyl)methanone (22364-54-1) → 2-naphthyltrimethylsilane (18052-85-2)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel⁽⁰⁾; 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene; In toluene; at 160 ℃; for 18h; Glovebox; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.joc.0c00772

upstream raw materials:

chloro-trimethyl-silane

2-chloronaphthalene

2-naphthyllithium

2-bromonaphthalene

Downstream raw materials:

2-fluoronaphthalene

1-naphthalenecarboxylic acid

naphthalene-2-carboxylate

2-phenyl-2-trimethylsilyloxypropanenitrile