13,14-Hexacosanedione

Base Information

• Chemical Name: 13,14-Hexacosanedione
• CAS No.: 18229-38-4
• Molecular Formula: C26H50O2
• Mol file: 18229-38-4.mol

Synonyms:

Chemical Property of 13,14-Hexacosanedione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 13,14-Hexacosanedione

There total 4 articles about 13,14-Hexacosanedione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

oxalyl dichloride (79-37-8) + 1-dodecylbromide (143-15-7) → 13,14-hexacosanedione (18229-38-4)

Guidance literature:

1-dodecylbromide; With magnesium; In tetrahydrofuran; at -78 ℃;

With copper(I) bromide; lithium bromide; In tetrahydrofuran; at -100 - -75 ℃;

oxalyl dichloride; In tetrahydrofuran; at -95 - -90 ℃; for 1h; Further stages.;

DOI:10.1021/jo0262255

Reference yield:

14-hydroxy-hexacosan-13-one (18229-14-6) → 13,14-hexacosanedione (18229-38-4)

Guidance literature:

With lead dioxide;

Reference yield:

2,6-didodecyl-[1,4]benzoquinone (42177-30-0) → 13,14-hexacosanedione (18229-38-4)

Guidance literature:

With benzene;

upstream raw materials:

14-hydroxy-hexacosan-13-one

2,6-didodecyl-[1,4]benzoquinone

oxalyl dichloride

1-dodecylbromide

Refernces

• 1、 Song, Suhee,Keum, Sangha,Lee, Ji-Hyun,Lee, Jihoon,Kim, Seungmin,Park, Seong Soo,Kim, Jin Young,Park, Sung Heum,Jin, Youngeup. "Photovoltaic polymers based on difluoroqinoxaline units with deep HOMO levels". . p. 1489 - 1497. Retrieved 2018.