[tris(2-diphenylphosphinoethyl)phosphine]nickel(I) perchlorate

Base Information

Chemical Name:[tris(2-diphenylphosphinoethyl)phosphine]nickel(I) perchlorate
CAS No.:76295-71-1
Molecular Formula:C₄₂H₄₂NiP₄*ClO₄
Molecular Weight:828.831
Hs Code.:

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Chemical Property of [tris(2-diphenylphosphinoethyl)phosphine]nickel(I) perchlorate

Chemical Property:

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Technology Process of [tris(2-diphenylphosphinoethyl)phosphine]nickel(I) perchlorate

There total 3 articles about [tris(2-diphenylphosphinoethyl)phosphine]nickel(I) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 23777-40-4
bis(triphenylphosphine)ethylenenickel⁽⁰⁾

: 23582-03-8
tris(2-diphenylphosphinoethyl)phosphine

: 143-66-8
sodium tetraphenyl borate

: 51778-20-2,58003-32-0
1,2,3-triphenylcyclopropenylium perchlorate

: (η3-C3Ph3)(tris(2-diphenylphosphinoethyl)phosphine)nickel tetraphenylborate

: 76295-71-1
[tris(2-diphenylphosphinoethyl)phosphine]nickel(I) perchlorate

Guidance literature:: In tetrahydrofuran; methanol; under N2, soln. of (C3Ph3)ClO4 in boiling MeOH was added to soln. of Ni-complex (molar ratio 1:1) in THF, 1 equiv of solid ligand was added, heated at 50°C, filtered, NaBPh4 was added to filtrate; filtered crystals washed with MeOH and light petroleum, dried under stream of N2; elem. anal.;
DOI:10.1039/DT9830002263

Reference yield:

: 23777-40-4
bis(triphenylphosphine)ethylenenickel⁽⁰⁾

: 23582-03-8
tris(2-diphenylphosphinoethyl)phosphine

: 1923-70-2
tetrabutylammonium perchlorate

: 76295-71-1
[tris(2-diphenylphosphinoethyl)phosphine]nickel(I) perchlorate

Guidance literature:: In tetrahydrofuran; methanol; under N2, soln. of NBu4ClO4 was added to soln. of Ni-complex in THF, solid ligand was added (molar ratio 1:1:1), heated at 50°C; mixt. of intractable products;
DOI:10.1039/DT9830002263