Silane, trimethyl[(3-nitrophenyl)ethynyl]-

Base Information

• Chemical Name: Silane, trimethyl[(3-nitrophenyl)ethynyl]-
• CAS No.: 183322-33-0
• Molecular Formula: C11H13NO2Si
• Molecular Weight: 219.315
• Mol file: 183322-33-0.mol

Synonyms:3-(trimethylsilylethynyl)nitrobenzene;trimethyl(3-nitrophenylethynyl)silane;3-trimethylsilylethynylnitrobenzene;3-[(trimethylsilyl)ethynyl]nitrobenzene;Trimethyl[(3-nitrophenyl)ethynyl]silane;

Chemical Property of Silane, trimethyl[(3-nitrophenyl)ethynyl]-

Chemical Property:

• Boiling Point: 272.3±32.0 °C(Predicted)
• PSA: 45.82000
• Density: 1.08±0.1 g/cm3(Predicted)
• LogP: 3.34690

Purity/Quality:

99% ^*data from raw suppliers

1-Nitro-3-[2-(trimethylsilyl)ethynyl]-benzene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, trimethyl[(3-nitrophenyl)ethynyl]-

There total 4 articles about Silane, trimethyl[(3-nitrophenyl)ethynyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

m-iodonitrobenzene (645-00-1) + trimethylsilylacetylene (1066-54-2) → 1-nitro-3-[2-(trimethylsilyl)ethynyl]benzene (183322-33-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; at 20 ℃;

Reference yield: 83.0%

m-nitrobromobenzene (585-79-5) + trimethylsilylacetylene (1066-54-2) → 1-nitro-3-[2-(trimethylsilyl)ethynyl]benzene (183322-33-0)

Guidance literature:

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; for 24h; Inert atmosphere; Reflux;

DOI:10.1055/s-0030-1260256

Reference yield:

dichlorobis(triphenylphonsphone)palladium + m-nitrobromobenzene (585-79-5) + copper(I) iodide (7681-65-4) + trimethylsilylacetylene (1066-54-2) → 1-nitro-3-[2-(trimethylsilyl)ethynyl]benzene (183322-33-0)

Guidance literature:

With triethylamine;

upstream raw materials:

m-iodonitrobenzene

trimethylsilylacetylene

m-nitrobromobenzene

copper(I) iodide

Downstream raw materials:

(Z)-1-(2-bromo-vinyl)-3-nitro-benzene

(E)-1-(2-bromo-vinyl)-3-nitro-benzene

1-(3-nitrophenyl)-2-phenylacetylene

3,3,3-trifluoro-1-(3-nitrophenyl)propan-1-one