2-Propenoic acid, 3-(phenylsulfonyl)-, methyl ester, (2E)-

Base Information

• Chemical Name: 2-Propenoic acid, 3-(phenylsulfonyl)-, methyl ester, (2E)-
• CAS No.: 1865-13-0
• Molecular Formula: C10H10O4S
• Molecular Weight: 226.253
• Mol file: 1865-13-0.mol

Synonyms:

Chemical Property of 2-Propenoic acid, 3-(phenylsulfonyl)-, methyl ester, (2E)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Propenoic acid, 3-(phenylsulfonyl)-, methyl ester, (2E)-

There total 16 articles about 2-Propenoic acid, 3-(phenylsulfonyl)-, methyl ester, (2E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

sodium benzenesulfonate (873-55-2) + propynoic acid methyl ester (922-67-8) → (Z)-β-phenylsulphonylacrylic acid methyl ester (1865-13-0,63068-63-3,91077-67-7)

Guidance literature:

With boric acid; tetra(n-butyl)ammonium hydrogensulfate; In tetrahydrofuran; water; for 12h; Ambient temperature;

DOI:10.1039/c39870001836

Reference yield: 88.0%

Methyl 2,3-dibromopropionate (1729-67-5) + sodium benzenesulfonate (873-55-2) → (E)-β-methoxycarbonylvinyl phenyl sulphone (1865-13-0)

Guidance literature:

In N,N-dimethyl-formamide; at 80 ℃; for 7h;

DOI:10.1055/s-2007-966039

Reference yield: 86.0%

maleic anhydride (108-31-6) + (cycloocta-1,5-diene)(methyl trans-β-(phenylsulfonyl)acrylate)nickel (91158-50-8) → (cycloocta-1,5-diene)(maleic anhydride)nickel (91158-57-5) + (E)-β-methoxycarbonylvinyl phenyl sulphone (1865-13-0)

Guidance literature:

In tetrahydrofuran; To a stirred soln. of complex in THF was added dropwise a soln. of ligand in THF at -20°C., the soln. was stirred for ca. 1 h (Ar atm.);; recrystd. from Et2O-THF at -20°C; elem. anal.;;

upstream raw materials:

Methyl 2,3-dibromopropionate

sodium benzenesulfonate

acrylic acid methyl ester

methyl (E)-3-(tributylstannyl)acrylate

Downstream raw materials:

methyl 3,3-dimethoxypropionate

dimethyl 3-benzenesulphonyl-2-pyrrolidinomethylidinylglutarate

(phenylsulfonyl)pentanone

methyl 3-(5-t-butyl-2-oxocyclohexyl)propenoate