9-Ethyl-3-(triphenylsilyl)carbazole

Base Information

• Chemical Name: 9-Ethyl-3-(triphenylsilyl)carbazole
• CAS No.: 18834-05-4
• Molecular Formula: C₃₂H₂₇NSi
• Molecular Weight: 453.659
• European Community (EC) Number: 659-355-0
• Nikkaji Number: J2.835.386C
• Mol file: 18834-05-4.mol

Synonyms:9-ETHYL-3-(TRIPHENYLSILYL)CARBAZOLE;SCHEMBL1479298;AKOS024432756;Triphenyl(9-ethyl-9H-carbazole-3-yl)silane

Chemical Property of 9-Ethyl-3-(triphenylsilyl)carbazole

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 453.191276400
• Heavy Atom Count: 34
• Complexity: 598

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN1C2=C(C=C(C=C2)[Si](C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5)C6=CC=CC=C61

Technology Process of 9-Ethyl-3-(triphenylsilyl)carbazole

There total 4 articles about 9-Ethyl-3-(triphenylsilyl)carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-ethylcarbazole (86-28-2) → 9-ethyl-3-triphenylsilanyl-carbazole (18834-05-4)

Guidance literature:

Multi-step reaction with 2 steps

1: water; potassium bromide; potassium bromate

2: butyl lithium; benzene; diethyl ether

With potassium bromate; n-butyllithium; diethyl ether; water; potassium bromide; benzene;

DOI:10.1021/jo01119a012

Reference yield:

3-bromo-9-ethyl-9H-carbazole (57102-97-3) + Triphenylsilyl chloride (76-86-8) → 9-ethyl-3-triphenylsilanyl-carbazole (18834-05-4)

Guidance literature:

With n-butyllithium; diethyl ether; benzene;

DOI:10.1021/jo01119a012

Reference yield:

3-bromo-9-ethyl-9H-carbazole (57102-97-3) + triphenylsilylkalium (15487-82-8,6735-25-7) → 9-ethyl-3-triphenylsilanyl-carbazole (18834-05-4)

Guidance literature:

With diethyl ether;

DOI:10.1021/jo01119a012

upstream raw materials:

3-bromo-9-ethyl-9H-carbazole

Triphenylsilyl chloride

triphenylsilylkalium

N-ethylcarbazole