Diazene, bis(3-methylphenyl)-, 1-oxide

Base Information

• Chemical Name: Diazene, bis(3-methylphenyl)-, 1-oxide
• CAS No.: 19618-06-5
• Molecular Formula: C₁₄H₁₄N₂O
• Molecular Weight: 226.278
• DSSTox Substance ID: DTXSID70393911
• Mol file: 19618-06-5.mol

Synonyms:19618-06-5;3,3'-Dimethylazoxybenzene;Diazene, bis(3-methylphenyl)-, 1-oxide;3,3''-AZOXYTOLUENE;(3-methylphenyl)-(3-methylphenyl)imino-oxidoazanium;di-m-tolyl-diazene N-oxide;DTXSID70393911;(Z)-1,2-dim-tolyldiazene oxide;AKOS024333710

Chemical Property of Diazene, bis(3-methylphenyl)-, 1-oxide

Chemical Property:

• Melting Point: 37 °C
• Boiling Point: 386.6±45.0 °C(Predicted)
• PSA: 41.11000
• Density: 1.1136 g/cm3(Temp: 21.6 °C)
• LogP: 4.75230
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 226.110613074
• Heavy Atom Count: 17
• Complexity: 277

Purity/Quality:

98% ^*data from raw suppliers

3,3'-AZOXYTOLUENE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=CC=C1)N=[N+](C2=CC=CC(=C2)C)[O-]

Technology Process of Diazene, bis(3-methylphenyl)-, 1-oxide

There total 37 articles about Diazene, bis(3-methylphenyl)-, 1-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-amino-3-methylbenzene (108-44-1) → N,N'-bis(3-methylphenyl)-diazene N-oxide (71297-97-7,116723-90-1,19618-06-5)

Guidance literature:

With dihydrogen peroxide; Na₁₂[WZn₃(H₂O)2(ZnW₉O₃₄)2]; at 75 ℃; for 7h;

DOI:10.1002/adsc.200303156

Reference yield: 96.0%

1-amino-3-methylbenzene (108-44-1) → 3,3'-dimethylazoxybenzene (19618-06-5,71297-97-7,116723-90-1)

Guidance literature:

With trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane; In ethanol; at 20 ℃; for 0.0833333h; Sonication; Green chemistry;

DOI:10.1007/s13738-013-0328-z

Reference yield: 94.0%

1-methyl-3-nitrobenzene (99-08-1) → 3,3'-dimethylazoxybenzene (19618-06-5,71297-97-7,116723-90-1)

Guidance literature:

With oxygen; ammonium chloride; zinc; In [bmim][BF₄]; water; at 20 ℃; for 16h;

DOI:10.1016/j.tetlet.2009.02.122

upstream raw materials:

1-methyl-3-nitrobenzene

N-(3-methylphenyl)hydroxylamine

N-Hydroxy-m-acetoacetanilid

1-amino-3-methylbenzene

Downstream raw materials:

N,N'-bis(3-methylphenyl)-diazene N-oxide

2-Methyl-4-m-tolylazo-phenol

3,3'-dimethylazobenzene

3,3'-dimethylhydrazobenzene

Refernces

• 1、 -. "Preparation of niobium or tantalum complex and application of niobium or tantalum complex in catalyzing aromatic amine to generate oxidized azobenzene compound". Paragraph 0068-0071. . Retrieved 2021/11/03.
• 2、 Yan, Ziqiang,Xie, Xiaoyu,Song, Qun,Ma, Fulei,Sui, Xinyu,Huo, Ziyu,Ma, Mingming. "Tandem selective reduction of nitroarenes catalyzed by palladium nanoclusters". supporting information. p. 1301 - 1307. Retrieved 2020/03/11.