Benzenethiol, pentafluoro-, mercury(2+) salt

Base Information

• Chemical Name: Benzenethiol, pentafluoro-, mercury(2+) salt
• CAS No.: 20364-76-5
• Molecular Formula: C6HF5S.1/2Hg
• Molecular Weight: 598.838
• Mol file: 20364-76-5.mol

Synonyms:

Chemical Property of Benzenethiol, pentafluoro-, mercury(2+) salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenethiol, pentafluoro-, mercury(2+) salt

There total 16 articles about Benzenethiol, pentafluoro-, mercury(2+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

pentafluorophenylthiol (771-62-0) + mercury(II) cyanide → bis(pentafluorophenylmercapto)mercury (20364-76-5)

Guidance literature:

In methanol; inert atm.; molar ratio Hg(CN)2:RSH 1:2, stirring, shaking (10 h); evapn., drying (100°C, 1E-4 mbar);

DOI:10.1002/(SICI)1521-3749(199912)625:12<2085::AID-ZAAC2085>3.3.CO;2-J

Reference yield: 87.0%

pentafluorophenylthiol (771-62-0) + mercury(II) diacetate (1600-27-7) → bis(pentafluorophenylmercapto)mercury (20364-76-5)

Guidance literature:

In water; HgOAc2 and HSC6F5 were combined in water, stirred overnight under N2; filtered, recrystd. from slowly cooled satd. hot toluene;

DOI:10.1021/ic0006908

Reference yield:

[(DME)3Nd(SC6F5)2]2[Hg2(μ-SC6F5)2(SC6F5)4]*2DME → neodymium(III) fluoride (13709-42-7) + bis(pentafluorophenylmercapto)mercury (20364-76-5)

Guidance literature:

In neat (no solvent, solid phase); heating to 700°C for 3 h in vacuo; XRD;

DOI:10.1021/ic049215q

upstream raw materials:

bis(pentafluorophenyl) disulfide

pentafluorophenylthiol

mercury(II) diacetate

mercury ion

Downstream raw materials:

(DME)2Er(SC₆F₅)3

pentafluorobenzenesulfenyl chloride

bis(pentafluorophenyl) disulfide

bis(pentafluorophenyl)mercury(II)