4-Bromo-2-(methylthio)thiazole

Base Information

Chemical Name:4-Bromo-2-(methylthio)thiazole
CAS No.:204513-62-2
Molecular Formula:C4H4BrNS2
Molecular Weight:210.118
Hs Code.:2934100090
European Community (EC) Number:640-556-7
DSSTox Substance ID:DTXSID80586014
Nikkaji Number:J449.924G
Wikidata:Q82478042
Mol file:204513-62-2.mol

Synonyms:204513-62-2;4-bromo-2-(methylthio)thiazole;4-Bromo-2-(thiomethyl)thiazole;4-bromo-2-methylsulfanyl-1,3-thiazole;2-Thiomethyl-4-bromothiazole;4-bromo-2-(methylthio)-1,3-thiazole;4-bromo-2-(methylsulfanyl)-1,3-thiazole;Thiazole, 4-bromo-2-(methylthio)-;MFCD07787376;SCHEMBL2560538;DTXSID80586014;YGCKEBOZMZSIDW-UHFFFAOYSA-N;4-Bromo-2-methylsulfanyl-thiazole;AKOS015834988;PS-3841;SY074035;DB-066212;CS-0037488;EN300-216111;W-206516

Suppliers and Price of 4-Bromo-2-(methylthio)thiazole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-Bromo-2-(thiomethyl)thiazole
250mg
$ 75.00

SynQuest Laboratories
4-Bromo-2-(methylthio)-1,3-thiazole
5 g
$ 365.00

SynQuest Laboratories
4-Bromo-2-(methylthio)-1,3-thiazole
1 g
$ 96.00

Sigma-Aldrich
4-Bromo-2-(thiomethyl)thiazole
1g
$ 135.00

Matrix Scientific
4-Bromo-2-(thiomethyl)thiazole 98%
25g
$ 1882.00

Matrix Scientific
4-Bromo-2-(thiomethyl)thiazole 98%
1g
$ 208.00

Matrix Scientific
4-Bromo-2-(thiomethyl)thiazole 98%
5g
$ 572.00

Crysdot
4-Bromo-2-(methylthio)thiazole 97%
5g
$ 301.00

AOBChem
4-Bromo-2-(thiomethyl)thiazole 97%
25g
$ 801.00

American Custom Chemicals Corporation
4-BROMO-2-(METHYLTHIO)-1,3-THIAZOLE 95.00%
5G
$ 1180.06

Total 20 raw suppliers

Chemical Property of 4-Bromo-2-(methylthio)thiazole

Chemical Property:

Vapor Pressure:0.00688mmHg at 25°C
Boiling Point:279.3oC at 760 mmHg
PKA:-0.35±0.10(Predicted)
Flash Point:122.7oC
PSA：66.43000
Density:1.81g/cm3
LogP:2.62750
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:208.89685
Heavy Atom Count:8
Complexity:80.4

Purity/Quality:

97% ^*data from raw suppliers

4-Bromo-2-(thiomethyl)thiazole ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 43
Safety Statements: 36/37

MSDS Files:

Useful:

Canonical SMILES:CSC1=NC(=CS1)Br

Technology Process of 4-Bromo-2-(methylthio)thiazole

There total 1 articles about 4-Bromo-2-(methylthio)thiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 4175-77-3
2,4-dibromo-1,3-thiazole

: 5188-07-8
sodium thiomethoxide

: 204513-62-2
4-bromo-2-(methylsulfanyl)-1,3-thiazole

Guidance literature:: In ethanol; at 25 ℃; for 3h; Inert atmosphere;

Reference yield: 92.0%

: 771-99-3
4-phenylpiperidine

: 204513-62-2
4-bromo-2-(methylsulfanyl)-1,3-thiazole

: 2-(methylthio)-4-(4-phenylpiperidin-1-yl)thiazole

Guidance literature:: With sodium t-butanolate; In tetrahydrofuran; at 40 ℃; for 16h; Sealed tube; Inert atmosphere;
DOI:10.1021/acs.oprd.9b00233

Reference yield: 59.0%

: 5467-74-3
4-Bromophenylboronic acid

: 204513-62-2
4-bromo-2-(methylsulfanyl)-1,3-thiazole

: 2103-93-7
2-methylmercapto-4-(4'-bromophenyl)thiazole

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In water; acetonitrile; at 100 ℃; for 1h; Microwave irradiation;
DOI:10.1021/jm200497t