(1-Phenylcyclohexyl) hydroperoxide

Base Information

• Chemical Name: (1-Phenylcyclohexyl) hydroperoxide
• CAS No.: 20614-61-3
• Molecular Formula: C12H16O2
• Molecular Weight: 192.258
• Mol file: 20614-61-3.mol

Synonyms:1-phenyl-cyclohexyl-hydroperoxide;Hydroperoxide,1-phenylcyclohexyl;Hydroperoxide,phenylcyclohexyl;1-Phenyl-cyclohexylhydroperoxid;cyclohexylbenzene-1-hydroperoxide;cyclohexylbenzene hydroperoxide;cyclohexyl-1-phenyl-1-hydroperoxide;

Chemical Property of (1-Phenylcyclohexyl) hydroperoxide

Chemical Property:

• Vapor Pressure: 9.9E-05mmHg at 25°C
• Boiling Point: 324.7oC at 760 mmHg
• Flash Point: 150.2oC
• PSA: 29.46000
• Density: 1.1g/cm3
• LogP: 3.33560

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1-Phenylcyclohexyl) hydroperoxide

There total 9 articles about (1-Phenylcyclohexyl) hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1-phenyl-1-cyclohexane (827-52-1,5379-26-0) → cyclohexyl-1-phenyl-1-hydroperoxide (20614-61-3)

Guidance literature:

With oxygen; eosin y; In acetonitrile; at 20 ℃; Irradiation;

DOI:10.1021/acs.joc.0c00385

Reference yield: 61.0%

1-phenylcyclohexanol (1589-60-2) → cyclohexyl-1-phenyl-1-hydroperoxide (20614-61-3)

Guidance literature:

With sulfuric acid; dihydrogen peroxide; In dichloromethane; water; at 0 - 25 ℃; for 12h; Schlenk technique; Inert atmosphere;

DOI:10.1039/d1cc03013b

Reference yield:

1-phenyl-1-cyclohexane (827-52-1,5379-26-0) → 1-phenylcyclohexanol (1589-60-2) + cyclohexyl-1-phenyl-1-hydroperoxide (20614-61-3) + 5-hydroxypentyl phenyl ketone (17851-49-9) + 4-phenyl-cyclohexanol (5769-13-1,7335-12-8,5437-46-7)

Guidance literature:

With oxygen; In chlorobenzene; at 130 ℃; for 6h; under 760.051 Torr; Temperature; Time; Reagent/catalyst; Catalytic behavior;

DOI:10.1016/j.catcom.2017.02.011

upstream raw materials:

1-phenylcyclohexanol

1-phenyl-1-cyclohexane

Cumene hydroperoxide

Isopropylbenzene

Downstream raw materials:

bis-(1-phenyl-cyclohexyl)-peroxide

caprophenone

cyclohexanone-oxime

phenol

Refernces

• 1、 Bai, Ming,Duan, Xin-Hua,Guo, Li-Na,Liu, Shuai,Sun, Qing-Xin,Xu, Peng-Fei. "Copper-catalyzed radical ring-opening halogenation with HX". supporting information. p. 8652 - 8655. Retrieved 2021/09/04.
• 2、 Gao, Pin,Wu, Hao,Yang, Jun-Cheng,Guo, Li-Na. "Iron-Catalyzed Decarboxylative Olefination of Unstrained Carbon-Carbon Bonds Relying on Alkoxyl Radical Induced Cascade". . p. 7104 - 7108. Retrieved 2019/09/30.