2'-(Methylthio)-[1,1'-biphenyl]-4-amine

Base Information

Chemical Name:2'-(Methylthio)-[1,1'-biphenyl]-4-amine
CAS No.:209731-61-3
Molecular Formula:C₁₃H₁₃NS
Molecular Weight:215.319
Hs Code.:2930909090
DSSTox Substance ID:DTXSID90445047
Wikidata:Q82263372
Mol file:209731-61-3.mol

Synonyms:209731-61-3;2'-(Methylthio)-[1,1'-biphenyl]-4-amine;4-Amino-2'-(methylthio)biphenyl;4-(2-methylsulfanylphenyl)aniline;SCHEMBL2785165;DTXSID90445047;4-Amino-2/'-(methylthio)biphenyl;MFCD20441865;AKOS015999632;SB76820;BS-22050;CS-0209549;2'-(Methylsulfanyl)[1,1'-biphenyl]-4-amine;A879322

Suppliers and Price of 2'-(Methylthio)-[1,1'-biphenyl]-4-amine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-Amino-2''-(methylthio)biphenyl
250mg
$ 50.00

TRC
4-Amino-2''-(methylthio)biphenyl
100mg
$ 45.00

Crysdot
2'-(Methylthio)-[1,1'-biphenyl]-4-amine 95+%
25g
$ 565.00

American Custom Chemicals Corporation
2'-(METHYLTHIO)-[1,1'-BIPHENYL]-4-AMINE 95.00%
5MG
$ 503.73

Alichem
2'-(Methylthio)-[1,1'-biphenyl]-4-amine
25g
$ 576.71

AK Scientific
4-Amino-2'-(methylthio)biphenyl
5g
$ 291.00

Total 9 raw suppliers

Chemical Property of 2'-(Methylthio)-[1,1'-biphenyl]-4-amine

Chemical Property:

PSA：51.32000
LogP:4.23890
XLogP3:3.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:215.07687059
Heavy Atom Count:15
Complexity:187

Purity/Quality:

97% ^*data from raw suppliers

4-Amino-2''-(methylthio)biphenyl ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CSC1=CC=CC=C1C2=CC=C(C=C2)N

Technology Process of 2'-(Methylthio)-[1,1'-biphenyl]-4-amine

There total 2 articles about 2'-(Methylthio)-[1,1'-biphenyl]-4-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 106-40-1
4-bromo-aniline

: 168618-42-6
(2-methylsulfanylphenyl)boronic acid

: 209731-61-3
2'-methylsulfanyl-biphenyl-4-ylamine

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutylammomium bromide; sodium carbonate; In toluene; for 5.5h; Heating;
DOI:10.1021/jm980405i

Reference yield:

: 100727-36-4
methyl (4'-nitro-[1,1'-biphenyl]-2-yl)sulfane

: 209731-61-3
2'-methylsulfanyl-biphenyl-4-ylamine

Guidance literature:: With hydrogenchloride; tin(ll) chloride;

Reference yield:

: 209731-61-3
2'-methylsulfanyl-biphenyl-4-ylamine

: 5-isoxazoleacetic acid, 3-<3-(aminoiminomethyl)phenyl>-5-<<<2'-(thiomethyl)<1,1'-biphenyl>-4-yl>amino>carbonyl>-4,5-dihydro-, methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: Et₃N / tetrahydrofuran / Ambient temperature

2: HCl gas / CHCl₃ / 12 h / 0 °C

3: NH₄OAc / methanol / 12 h / Ambient temperature

With hydrogenchloride; ammonium acetate; triethylamine; In tetrahydrofuran; methanol; chloroform;
DOI:10.1021/jm980405i