Stannane, (1,1-dimethylethoxy)trimethyl-

Base Information

• Chemical Name: Stannane, (1,1-dimethylethoxy)trimethyl-
• CAS No.: 21726-97-6
• Molecular Formula: C7H18OSn
• Molecular Weight: 236.929
• Mol file: 21726-97-6.mol

Synonyms:

Chemical Property of Stannane, (1,1-dimethylethoxy)trimethyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Stannane, (1,1-dimethylethoxy)trimethyl-

There total 3 articles about Stannane, (1,1-dimethylethoxy)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

trimethyltin bromide (1066-44-0) + tributyltin tert-butoxide (2724-79-0) → tributyltin bromide (1461-23-0) + trimethyltin tert-butoxide (21726-97-6)

Guidance literature:

by heating;

Reference yield:

N,N,N,N,-tetramethylethylenediamine (110-18-9) + trimethyltin(IV)chloride (1066-45-1) → trans-1-(dimethylamino)-2-(trimethylstannyl)ethene (109862-85-3) + 1-(dimethylamino)-1-(trimethylstannyl)ethene (109862-84-2) + hexamethyldistannane (661-69-8) + (dimethylamino)trimethyltin (993-50-0) + trimethyltin tert-butoxide (21726-97-6)

Guidance literature:

With n-butyllithium; potassium tert-butylate; In pentane; byproducts: Sn(CH3)4; under exclusion of oxygen and moisture, reaction of Me2NC2H4NMe2 with two equivalents of n-C4H9Li/tert-BuOK (mixing at -78°C, then warming to room temp.), stirring for 12 h, cooling to -60°C, addn. of Me3SnCl, thawing, hydrolysis; after sepn. of solid a liquid is obtained, removal of solvents, distillation, three fractions (25°C/13-133 Pa, 25°C/0.1 Pa, 70°C/0.1 Pa) with various product ratios are obtained; total yield of H2CC(NMe2)SnMe3 11%;

Reference yield:

CH2CHCH2CH2OCH2SeC6H5 + di-tert-butyl peroxide (110-05-4) + hexamethyldistannane (661-69-8) → trimethylstannyl phenyl selenide (4848-71-9) + trimethyltin tert-butoxide (21726-97-6)

Guidance literature:

In further solvent(s); Irradiation (UV/VIS); a soln. of the reagents in cyclopropane was irradiated with UV light at temp. above 220 K; monitoring by ESR spectra; Kinetics;

upstream raw materials:

di-tert-butyl peroxide

hexamethyldistannane

N,N,N,N,-tetramethylethylenediamine

trimethyltin(IV)chloride

Downstream raw materials:

(E)-trimethyl(1-phenyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-1-en-1-yl)stannane