alpha-Bromoallocinnamic acid methyl ester

Base Information

Chemical Name:alpha-Bromoallocinnamic acid methyl ester
CAS No.:21788-35-2
Molecular Formula:C₁₀H₉BrO₂
Molecular Weight:241.084
Hs Code.:
DSSTox Substance ID:DTXSID90344208
Nikkaji Number:J192.697G
Mol file:21788-35-2.mol

Synonyms:DTXSID90344208;alpha-Bromoallocinnamic acid methyl ester;Methyl (2E)-2-bromo-3-phenyl-2-propenoate;2-bromo-3-phenyl-cis-prop-2-enoic acid methyl ester

Suppliers and Price of alpha-Bromoallocinnamic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of alpha-Bromoallocinnamic acid methyl ester

Chemical Property:

Vapor Pressure:0.002mmHg at 25°C
XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:239.97859
Heavy Atom Count:13
Complexity:205

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C(=CC1=CC=CC=C1)Br
Isomeric SMILES:COC(=O)/C(=C\C1=CC=CC=C1)/Br

Technology Process of alpha-Bromoallocinnamic acid methyl ester

There total 20 articles about alpha-Bromoallocinnamic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 3222-05-7
methyl tribromoacetate

: 100-52-7
benzaldehyde

: 24127-62-6,21788-35-2,21788-36-3
methyl 2-bromo-3-phenylacrylate

Guidance literature:: With chromium dichloride; In tetrahydrofuran; at 23 ℃;
DOI:10.1021/jo061445u

Reference yield: 96.0%

: 103-26-4,1754-62-7
Methyl cinnamate

: 24127-62-6,21788-35-2,21788-36-3
methyl 2-bromo-3-phenylacrylate

Guidance literature:: Methyl cinnamate; With bromine; In dichloromethane; at 0 - 20 ℃; for 16h;

With triethylamine; In dichloromethane; at 20 ℃; for 16h;
DOI:10.1039/d0gc03081c

Reference yield: 94.0%

: 100-52-7
benzaldehyde

: 287481-44-1
methyl 2-(bis(2,2,2-trifluoroethoxy)phosphoryl)-2-bromoacetate

: 24127-62-6,21788-35-2,21788-36-3
methyl 2-bromo-3-phenylacrylate

Guidance literature:: methyl 2-(bis(2,2,2-trifluoroethoxy)phosphoryl)-2-bromoacetate; With 18-crown-6 ether; potassium tert-butylate; In tetrahydrofuran; acetonitrile; at -78 ℃; for 0.5h;

benzaldehyde; In tetrahydrofuran; at -78 ℃; for 0.333333h; Further stages.;
DOI:10.1021/ol006074x