1-Azidopropane

Base Information

• Chemical Name: 1-Azidopropane
• CAS No.: 22293-25-0
• Molecular Formula: C3H7N3
• Molecular Weight: 85.1087
• Hs Code.: 2929909090
• DSSTox Substance ID: DTXSID60496682
• Nikkaji Number: J375.180E
• Wikidata: Q6951400
• Wikipedia: n-Propyl azide,N-Propyl_azide
• Mol file: 22293-25-0.mol

Synonyms:1-Azidopropane;22293-25-0;N-Propyl azide;propyl azide;1-Azido propane;DTXSID60496682;TVPPZASKIXGUJQ-UHFFFAOYSA-N;AKOS010630666;Q6951400;F8882-5549

Chemical Property of 1-Azidopropane

Chemical Property:

• PSA: 49.75000
• LogP: 1.15946
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 85.063997236
• Heavy Atom Count: 6
• Complexity: 62.4

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCN=[N+]=[N-]

Technology Process of 1-Azidopropane

There total 2 articles about 1-Azidopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl n-propylnitrosocarbamate (19935-85-4) → propan-1-ol (71-23-8) + n-propyl azide (22293-25-0) + 2-azidopropane (691-57-6) + isopropyl alcohol (67-63-0,8013-70-5)

Guidance literature:

With sodium azide; at 25 ℃; Mechanism; Product distribution; pH 8.0, 0.1 M sodium phosphate buffer;

DOI:10.1021/ja00319a027

Reference yield:

(Z)-potassium propanediazotate (87549-57-3,98114-61-5,98114-64-8) → propan-1-ol (71-23-8) + n-propyl azide (22293-25-0) + 2-azidopropane (691-57-6) + isopropyl alcohol (67-63-0,8013-70-5)

Guidance literature:

With sodium azide; potassium tert-butylate; at 25 ℃; Mechanism;

DOI:10.1021/ja00319a027

Reference yield: 95.0%

n-propyl azide (22293-25-0) + prop-2-ynyl 2-acetamido-2-deoxy-4-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-6-O-tert-butyldiphenylsilyl-β-D-glucopyranoside → 4-[2-acetamido-2-deoxy-4-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-6-O-tert-butyldiphenylsilyl-β-D-glucopyranosyloxymethyl]-1-propyl-1H-1,2,3-triazole

Guidance literature:

With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In tetrahydrofuran; water; at 20 ℃; for 12h;

DOI:10.1002/cbic.201402474

upstream raw materials:

methyl n-propylnitrosocarbamate

(Z)-potassium propanediazotate

Downstream raw materials:

C₂₂H₂₁Cl₂N₂O₂P

1-propyl-4-phenyl-1H-1,2,3-triazole

1-propyl-4-(p-tolyl)-1H-1,2,3-triazole

4-((1-propyl-1H-1,2,3-triazol-4-yl)methoxy)benzaldehyde