1-Methyl-2-propenylphenyl ether

Base Information

• Chemical Name: 1-Methyl-2-propenylphenyl ether
• CAS No.: 22509-78-0
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Hs Code.: 2909309090
• Mol file: 22509-78-0.mol

Synonyms:1-Methyl-2-propenylphenyl ether;Ether,1-methylallyl phenyl;Benzene,[(1-methyl-2-propenyl)oxy];

Chemical Property of 1-Methyl-2-propenylphenyl ether

Chemical Property:

• Boiling Point: 42.9-43.0 °C(Press: 0.8 Torr)
• PSA: 9.23000
• Density: 0.935±0.06 g/cm3(Predicted)
• LogP: 2.63990

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Methyl-2-propenylphenyl ether

There total 13 articles about 1-Methyl-2-propenylphenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

2-hydroxy-3-butene (598-32-3) + potassium phenyltrifluoborate → (but-3-en-2-yloxy)benzene (22509-78-0)

Guidance literature:

potassium phenyltrifluoborate; With dmap; copper diacetate; 4 A molecular sieve; In dichloromethane; at 20 ℃; for 0.0833333h;

2-hydroxy-3-butene; With oxygen; In dichloromethane; at 20 ℃; for 24h;

DOI:10.1021/ol034454n

Reference yield:

3-bromo-1-butene (22037-73-6) + phenol (108-95-2,27073-41-2) → (but-3-en-2-yloxy)benzene (22509-78-0)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; 1.) 3 h, 2.) 60 - 65 deg C, 3 h, 3.) RT, overnight;

DOI:10.1021/jm00371a003

Reference yield:

2-chloro-3-butene (563-52-0,35729-37-4) + phenol (108-95-2,27073-41-2) → (E)-(but-2-en-1-yloxy)benzene (14309-16-1) + (but-3-en-2-yloxy)benzene (22509-78-0) + (Z)-(but-2-en-1-yloxy)benzene (66527-92-2)

Guidance literature:

With potassium carbonate; tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate; In acetone; at 20 ℃; for 40h; Title compound not separated from byproducts.;

DOI:10.1002/adsc.200404023

upstream raw materials:

2-chloro-3-butene

phenol

2-butenyl phenyl carbonate

1-methyl-propenyl phenyl carbonate

Downstream raw materials:

ortho-butylphenol

2,3-Dihydro-3-methylbenzofurane-2-carboxylic acid

2-(but-3-en-2-yl)phenol

(R)-3-phenyl-1-butene