(3S)-3-Phenyl-1-butene

Base Information

• Chemical Name: (3S)-3-Phenyl-1-butene
• CAS No.: 58717-85-4
• Molecular Formula: C10H12
• Molecular Weight: 132.205
• Mol file: 58717-85-4.mol

Synonyms:[(S)-1-methylallyl]benzene;[(1S)-1-methylprop-2-en-1-yl]benzene;(+)-(S)-3-phenyl-1-butene;(S)-3-phenylbut-1-ene;(1-Methyl-allyl)-benzene;(S)-(but-3-en-2-yl)benzene;(+)-1-((S)-but-3-en-2-yl)benzene;

Chemical Property of (3S)-3-Phenyl-1-butene

Chemical Property:

• PSA: 0.00000
• LogP: 2.97610

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (3S)-3-Phenyl-1-butene

There total 51 articles about (3S)-3-Phenyl-1-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

methylmagnesium bromide (75-16-1) + Cinnamyl bromide (4392-24-9) → trans-1-phenyl-1-butene (1005-64-7) + (S)-3-phenyl-1-butene (58717-85-4)

Guidance literature:

With copper(I) bromide dimethylsulfide complex; (R,S)-Taniaphos; In diethyl ether; dichloromethane; at -75 ℃; for 4h;

DOI:10.1039/b513887f

Reference yield: 91.0%

methylmagnesium bromide (75-16-1) + 3-bromo-1-phenyl-1-propenyl bromide (4392-24-9) → (S)-3-phenyl-1-butene (58717-85-4)

Guidance literature:

With copper(I) bromide dimethylsulfide complex; (R,R)-Taniaphos; In diethyl ether; dichloromethane; at -75 ℃; for 16h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;

DOI:10.1021/jo8010649

Reference yield: 83.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + ethene (74-85-1) → (S)-3-phenyl-1-butene (58717-85-4)

Guidance literature:

With C₃H₆BrNi*C₄₄H₃₄NO₂P; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; In dichloromethane; at 20 ℃; for 0.283333h; optical yield given as %ee; enantioselective reaction;

DOI:10.1002/adsc.200900559

upstream raw materials:

Vinyl bromide

1-phenylethylmagnesium chloride

(α-methylbenzyl)zinc chloride

chloroethylene

Downstream raw materials:

(-)-(S,E)-methyl 4-phenylpent-2-enoate

(-)-(S,E)-5-phenyl-hex-3-en-2-one

(-)-S-ethyl (S,E)-4-phenyl-pent-2-enethioate

(-)-N,4-dimethyl-N-<<(E)-3-phenyl-2-butenyl>sulfinyl>-benzenesulfonamide