Pyrrolidine, 1,1'-(phenylphosphinidene)bis-

Base Information

• Chemical Name: Pyrrolidine, 1,1'-(phenylphosphinidene)bis-
• CAS No.: 22859-48-9
• Molecular Formula: C14H21N2P
• Molecular Weight: 248.308
• DSSTox Substance ID: DTXSID20423075
• Nikkaji Number: J1.395.758D
• Wikidata: Q82235190
• Mol file: 22859-48-9.mol

Synonyms:Pyrrolidine, 1,1'-(phenylphosphinidene)bis-;22859-48-9;Phenyldipyrrolizinophosphine;SCHEMBL11679024;DTXSID20423075

Chemical Property of Pyrrolidine, 1,1'-(phenylphosphinidene)bis-

Chemical Property:

• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 248.144235676
• Heavy Atom Count: 17
• Complexity: 212

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCN(C1)P(C2=CC=CC=C2)N3CCCC3

Technology Process of Pyrrolidine, 1,1'-(phenylphosphinidene)bis-

There total 1 articles about Pyrrolidine, 1,1'-(phenylphosphinidene)bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pyrrolidine (123-75-1) + Dichlorophenylphosphine (644-97-3) → phenyl bis(N-pyrrolidinyl)phosphine (22859-48-9)

Guidance literature:

In diethyl ether;

DOI:10.1039/b108467d

Reference yield: 99.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + phenyl bis(N-pyrrolidinyl)phosphine (22859-48-9) → cis-dichloro-bis(phenyl(dipyrrolidinyl)phosphine)platinum(II) (317331-02-5)

Guidance literature:

In not given; Pt(cod)Cl2 with 2 equivs phenyl bis(N-pyrrolidinyl)phosphine;

DOI:10.1039/b004893n

Reference yield: 99.0%

Fp(acetonitrile)(tetrafluoroborate) (32824-71-8) + phenyl bis(N-pyrrolidinyl)phosphine (22859-48-9) → dicarbonyl-cyclopentadienyl-(phenyl(dipyrrolidinyl)phosphine)iron tetrafluoroborate (444105-06-0)

Guidance literature:

In dichloromethane; Fe-complex and ligand were refluxed in CH2Cl2 for 2 h under N2; solvent was reduced, Et2O was added, filtered, washed with Et2O and hexane; elem. anal.;

DOI:10.1039/b108467d

upstream raw materials:

pyrrolidine

Dichlorophenylphosphine

Downstream raw materials:

cis-dichloro-bis(phenyl(dipyrrolidinyl)phosphine)platinum(II)

trans-((C₆H₅)(C₄H₈N)2P)2Rh(CO)Cl

dicarbonyl-cyclopentadienyl-(phenyl(dipyrrolidinyl)phosphine)iron tetrafluoroborate

carbonyl-cyclopentadienyl-iodo-(phenyl(dipyrrolidinyl)phosphine)iron