Palladium, diiodobis(triphenylphosphine)-

Base Information

• Chemical Name: Palladium, diiodobis(triphenylphosphine)-
• CAS No.: 23523-32-2
• Molecular Formula: C₃₆H₃₀I₂P₂Pd
• Molecular Weight: 884.811
• Mol file: 23523-32-2.mol

Synonyms:

Chemical Property of Palladium, diiodobis(triphenylphosphine)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Palladium, diiodobis(triphenylphosphine)-

There total 32 articles about Palladium, diiodobis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

triphenylphosphine (603-35-0) + palladium(II) iodide (7790-38-7) → trans-diiodobis(triphenylphosphine)palladium(II) (23523-32-2,22180-54-7)

Guidance literature:

In acetonitrile; all manipulations under Ar atm.; PdI2 suspended in warm MeCN, soln. of Pcompd. added to suspension at room temp., stirred for 1 h; ppt. filtered off, washed with MeCN, dried under vac.;

DOI:10.1515/znb-2004-0212

Reference yield: 90.0%

bis-triphenylphosphine-palladium(II) chloride (13965-03-2) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → diiodobis(triphenylphosphino)palladium(II) (23523-32-2,22180-54-7)

Guidance literature:

In dichloromethane; water; at 20 ℃; for 8h;

Reference yield: 90.0%

tetrakis(triphenylphosphine) palladium(0) (14221-01-3) + 1-iodo-2-phenylethyne (932-88-7) → trans-diiodobis(triphenylphosphine)palladium(II) (23523-32-2,22180-54-7)

Guidance literature:

In diethyl ether; N2-atmosphere; excess of alkyne, stirring at room temp. for 24 h; collection (filtration), washing (Et2O), drying (vac.);

DOI:10.1039/DT9780001577

upstream raw materials:

tetrakis(triphenylphosphine) palladium⁽⁰⁾

iodobenzene

9-iodo-m-carborane

triphenylphosphine

Downstream raw materials:

[PdI₂(P(C₆H₅)3)]2

[(CH₃)2C₆H₅P]3PdI⁽¹⁺⁾

Iodo(diethyldithiocarbamato)(triphenylphosphin)palladium(II)

N(C₄H₉)4⁽¹⁺⁾*PdI₃(P(C₆H₅)3)^(1-)=[N(C₄H₉)4][PdI₃(P(C₆H₅)3)]