2-Propenoic acid, 3,3'-(1,4-phenylene)bis-, diethyl ester

Base Information

• Chemical Name: 2-Propenoic acid, 3,3'-(1,4-phenylene)bis-, diethyl ester
• CAS No.: 23746-57-8
• Molecular Formula: C16H18O4
• Molecular Weight: 274.317
• European Community (EC) Number: 241-150-9
• UNII: 07BT5G3526
• DSSTox Substance ID: DTXSID10892014
• Nikkaji Number: J62.840I,J2.216.902E
• Wikidata: Q81981935
• Mol file: 23746-57-8.mol

Synonyms:1,4-Phenylenediacrylic Acid Diethyl Ester;17088-28-7;diethyl p-phenylenediacrylate;2-Propenoic acid, 3,3'-(1,4-phenylene)bis-, diethyl ester;Diethyl 1,4-Phenylenediacrylate;23746-57-8;UNII-07BT5G3526;p-Benzenediacrylic acid, diethyl ester, (E,E)-;07BT5G3526;p-Benzenediacrylic acid, diethyl ester;p-Phenylenediacrylic acid diethyl ester;Diethyl 3,3'-(1,4-phenylene)bisacrylate;1,4-Bis(2-ethoxycarbonylethenyl)benzene;J62.840I;2-Propenoic acid, 3,3'-(1,4-phenylene)bis-, 1,1'-diethyl ester;diethyl 3,3'-(1,4-phenylene)(2E,2'E)-diacrylate;2-Propenoic acid, 3,3'-(1,4-phenylene)bis-, diethyl ester, (E,E)-;ethyl (E)-3-[4-[(E)-3-ethoxy-3-oxoprop-1-enyl]phenyl]prop-2-enoate;2-Propenoic acid, 3,3'-(1,4-phenylene)bis-, 1,1'-diethyl ester, (2E,2'E)-;C16H18O4;SCHEMBL10939791;DTXSID10892014;QYGWZBFQWUBYAT-WGDLNXRISA-N;MFCD00017521;AS-65264;P1345;T71912;3,3'-(p-Phenylene)bis(acrylic acid ethyl) ester;A881979;(alphaE,alpha'E)-Benzene-1,4-diacrylic acid diethyl ester;N5-[(9H-FLUOREN-9-YLMETHOXY)CARBONYL]-D-ORNITHINE;3-[4-(2-Ethoxycarbonyl-vinyl)-phenyl]-acrylic acid ethyl ester;ethyl (2E)-3-{4-[(1E)-3-ethoxy-3-oxoprop-1-en-1-yl]phenyl}prop-2-enoate

Chemical Property of 2-Propenoic acid, 3,3'-(1,4-phenylene)bis-, diethyl ester

Chemical Property:

• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 274.12050905
• Heavy Atom Count: 20
• Complexity: 327

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCOC(=O)C=CC1=CC=C(C=C1)C=CC(=O)OCC
• Isomeric SMILES: CCOC(=O)/C=C/C1=CC=C(C=C1)/C=C/C(=O)OCC

Technology Process of 2-Propenoic acid, 3,3'-(1,4-phenylene)bis-, diethyl ester

There total 8 articles about 2-Propenoic acid, 3,3'-(1,4-phenylene)bis-, diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

diethoxyphosphoryl-acetic acid ethyl ester (867-13-0) + terephthalaldehyde, (623-27-8) → diethyl (2E,2′E)-3,3′-benzene-1,4-diylbis-prop-2-enoate (23746-57-8)

Guidance literature:

With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.5h;

DOI:10.1016/j.jfluchem.2007.05.004

Reference yield: 93.0%

hydrogen ethyl malonate (1071-46-1) + terephthalaldehyde, (623-27-8) → diethyl (2E,2′E)-3,3′-benzene-1,4-diylbis-prop-2-enoate (23746-57-8)

Guidance literature:

With piperidine; dmap; In N,N-dimethyl-formamide; at 25 ℃;

DOI:10.1002/adsc.200505196

Reference yield: 68.0%

diethoxyphosphoryl-acetic acid ethyl ester (867-13-0) + diethyl terephthalate (636-09-9) → diethyl (2E,2′E)-3,3′-benzene-1,4-diylbis-prop-2-enoate (23746-57-8)

Guidance literature:

diethyl terephthalate; With {μ-ClIr(cyclooctene)2}2; H₂SiEt₂; In dichloromethane; at 20 ℃; for 8h; Inert atmosphere;

diethoxyphosphoryl-acetic acid ethyl ester; With potassium trimethylsilonate; In tetrahydrofuran; at 20 ℃; for 0.5h;

DOI:10.1021/acs.orglett.5b02901

upstream raw materials:

1,4-phenylenediacrylic acid

ethanol

diethoxyphosphoryl-acetic acid ethyl ester

terephthalaldehyde,

Downstream raw materials:

3-[4-(2-ethoxycarbonyl-ethyl)-phenyl]-propionic acid ethyl ester

3t,3't-p-phenylene-di-acrylic acid dihydrazide

1,4-bis(3-hydroxy-1-(E)-propenyl)benzene

1,4-bis((E)-3-(methoxymethoxy)prop-1-enyl)benzene