1,2-DIMETHOXY-4,5-DINITROBENZENE

Base Information

• Chemical Name: 1,2-DIMETHOXY-4,5-DINITROBENZENE
• CAS No.: 3395-03-7
• Molecular Formula: C8H8N2O6
• Molecular Weight: 228.161
• Hs Code.: 2909309090
• Mol file: 3395-03-7.mol

Synonyms:Veratrole,4,5-dinitro- (6CI);1,2-Dimethoxy-4,5-dinitrobenzene;1,2-Dinitro-4,5-dimethoxybenzene;4,5-Dimethoxy-1,2-dinitrobenzene;4,5-Dinitro-1,2-dimethoxybenzene;4,5-Dinitroveratrol;4,5-Dinitroveratrole;NSC 10114;NSC 46825;NSC 93402;

Chemical Property of 1,2-DIMETHOXY-4,5-DINITROBENZENE

Chemical Property:

• Appearance/Colour: Yellow Powder
• Vapor Pressure: 1.43E-06mmHg at 25°C
• Melting Point: 131-134 °C
• Refractive Index: 1.567
• Boiling Point: 410.4 °C at 760 mmHg
• Flash Point: 205.7 °C
• PSA: 26.30000
• Density: 1.416 g/cm³
• LogP: 1.47980
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

1,2-Dimethoxy-4,5-dinitrobenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 5-20/21/22
• Safety Statements: 22-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-DIMETHOXY-4,5-DINITROBENZENE

There total 32 articles about 1,2-DIMETHOXY-4,5-DINITROBENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,2-dimethoxybenzene (91-16-7) → 4,5-dimethoxy-1,2-dinitrobenzene (3395-03-7)

Guidance literature:

With nitric acid; at 0 - 80 ℃; for 2h;

DOI:10.1039/c5ra25590b

Reference yield: 95.0%

3,4-dimethoxynitrobenzene (709-09-1) → 4,5-dimethoxy-1,2-dinitrobenzene (3395-03-7)

Guidance literature:

With sulfuric acid; potassium nitrate; at -5 - 0 ℃; for 0.5h;

DOI:10.1016/0223-5234(91)90199-W

Reference yield: 40.0%

1,2-dimethoxybenzene (91-16-7) → 3,4-dimethoxynitrobenzene (709-09-1) + 4,5-dimethoxy-1,2-dinitrobenzene (3395-03-7)

Guidance literature:

With Nitrogen dioxide; In acetonitrile; for 2.5h; Ambient temperature;

upstream raw materials:

1,2-dimethoxybenzene

3,4-dimethoxynitrobenzene

4',5'-dimethoxy-2'-nitroacetophenone

4-iodo-5-nitro-1,2-dimethoxybenzene

Downstream raw materials:

3,4,10,11-tetramethoxy-6,6a,7,8-tetrahydro-benzo[b]chromeno[4,3-e][1,4]diazepine

N-methyl-4,5-dinitro-2-methoxyaniline

5,6-dimethoxy-2,1,3-benzoxadiazole

N-n-butyl-4,5-dinitro-2-methoxyaniline

Refernces

• 1、 Dai, Lu,Li, Jiani,Li, Pengfei,Li, Shuai,Liu, Yanze,Lv, Jianning,Wang, Bo,Yin, Anxiang,Zhu, Zhejiaji. "The Synthesis of Hexaazatrinaphthylene-Based 2D Conjugated Copper Metal-Organic Framework for Highly Selective and Stable Electroreduction of CO2 to Methane". supporting information. p. 16409 - 16415. Retrieved 2021/06/27.
• 2、 -. "Polyhydroxy compound as well as preparation method and application thereof". Paragraph 0065-0069. . Retrieved 2021/10/27.