4beta-Phenyl-5alpha-methyl-1,3-dioxane

Base Information

Chemical Name:4beta-Phenyl-5alpha-methyl-1,3-dioxane
CAS No.:2418-49-7
Molecular Formula:C₁₁H₁₄O₂
Molecular Weight:178.231
Hs Code.:
DSSTox Substance ID:DTXSID901270192
Nikkaji Number:J1.838.992D
Mol file:2418-49-7.mol

Synonyms:DTXSID901270192;4beta-Phenyl-5alpha-methyl-1,3-dioxane;rel-(4R,5R)-5-Methyl-4-phenyl-1,3-dioxane;2418-49-7

Suppliers and Price of 4beta-Phenyl-5alpha-methyl-1,3-dioxane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 4beta-Phenyl-5alpha-methyl-1,3-dioxane

Chemical Property:

XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:178.099379685
Heavy Atom Count:13
Complexity:152

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1COCOC1C2=CC=CC=C2
Isomeric SMILES:C[C@@H]1COCO[C@H]1C2=CC=CC=C2

Technology Process of 4beta-Phenyl-5alpha-methyl-1,3-dioxane

There total 2 articles about 4beta-Phenyl-5alpha-methyl-1,3-dioxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 873-66-5
1-propenylbenzene

: 2033-27-4,2418-49-7,5663-20-7,97991-52-1
trans-5-methyl-4-phenyl-1,3-dioxane

: 2033-27-4,2418-49-7,5663-20-7,97991-52-1
trans-5-methyl-4-phenyl-1,3-dioxane

Guidance literature:: With 1,1,1-trifluoro-N-((11bS)-4-(((11bS)-4-oxido-9,14-bis(perfluoropropan-2-yl)-2,6-bis(4- (trifluoromethyl)phenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)imino)-9,14-bis(perfluoropropan-2-yl)-2,6-bis(4-(trifluoromethyl)phenyl)-4λ5-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)methanesulfonamide; In cyclohexane; at 25 ℃; for 120h; Overall yield = 25 percent; Optical yield = 15 percent ee; diastereoselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/jacs.1c10245

Reference yield:

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 873-66-5
1-propenylbenzene

: 2033-27-4,2418-49-7,5663-20-7,97991-52-1
trans-5-methyl-4-phenyl-1,3-dioxane

: 2033-27-4,2418-49-7,5663-20-7,97991-52-1
trans-5-methyl-4-phenyl-1,3-dioxane

Guidance literature:: With 1,1,1-trifluoro-N-((11bS)-4-(((11bS)-4-oxido-9,14-bis(perfluoropropan-2-yl)-2,6-bis(4- (trifluoromethyl)phenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)imino)-9,14-bis(perfluoropropan-2-yl)-2,6-bis(4-(trifluoromethyl)phenyl)-4λ5-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)methanesulfonamide; In cyclohexane; at 25 ℃; for 120h; Overall yield = 25 percent; Optical yield = 15 percent ee; diastereoselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/jacs.1c10245