α-Rh(AsC2H5(C6H5)2)3HCl2

Base Information

• Chemical Name: α-Rh(AsC2H5(C6H5)2)3HCl2
• CAS No.: 55331-53-8
• Molecular Formula: C₄₂H₄₆As₃Cl₂Rh
• Molecular Weight: 949.404
• Mol file: 55331-53-8.mol

Synonyms:

Chemical Property of α-Rh(AsC2H5(C6H5)2)3HCl2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-Rh(AsC2H5(C6H5)2)3HCl2

There total 1 articles about α-Rh(AsC2H5(C6H5)2)3HCl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + rhodium(III) chloride trihydrate + ethyldiphenylarsine (715-94-6) → α-Rh(AsC2H5(C6H5)2)3HCl2 (55331-53-8)

Guidance literature:

In hydrogenchloride; ethanol; refluxing of Rh salt in HCl with the ligand in H3PO2 in refluxing ethanol;

DOI:10.1016/0022-1902(74)80159-4

Reference yield:

perchloric acid (7601-90-3) + 1,10-Phenanthroline (66-71-7) + β-Rh(AsC2H5(C6H5)2)3HCl2 (55331-53-8) → {Rh(AsC2H5(C6H5)2)2(C6H4N)2Cl2}(1+)*ClO4(1-)={Rh(AsC2H5(C6H5)2)2(C6H4N)2Cl2}ClO4 (61475-67-0)

Guidance literature:

In perchloric acid; ethanol; aq. HClO4; with concd. HClO4; refluxing;

DOI:10.1016/0022-1902(74)80159-4

Reference yield:

[2,2]bipyridinyl (366-18-7) + perchloric acid (7601-90-3) + α-Rh(AsC2H5(C6H5)2)3HCl2 (55331-53-8) → {Rh(AsC2H5(C6H5)2)2(C5H4N)2HCl}(1+)*ClO4(1-)={Rh(AsC2H5(C6H5)2)2(C5H4N)2HCl}ClO4 (61475-59-0)

Guidance literature:

In perchloric acid; ethanol; aq. HClO4; refluxing; with concd. HClO4;

DOI:10.1016/0022-1902(74)80159-4

upstream raw materials:

hydrogenchloride

ethyldiphenylarsine

Downstream raw materials:

{Rh(AsC₂H₅(C₆H₅)2)2(C₅H₄N)2HCl}⁽¹⁺⁾*ClO₄^(1-)={Rh(AsC₂H₅(C₆H₅)2)2(C₅H₄N)2HCl}ClO₄

{Rh(AsC₂H₅(C₆H₅)2)2(C₅H₄N)2Cl₂}⁽¹⁺⁾*ClO₄^(1-)={Rh(AsC₂H₅(C₆H₅)2)2(C₅H₄N)2Cl₂}ClO₄

{Rh(AsC₂H₅(C₆H₅)2)2(C₆H₄N)2HCl}⁽¹⁺⁾*ClO₄^(1-)={Rh(AsC₂H₅(C₆H₅)2)2(C₆H₄N)2HCl}ClO₄

{Rh(AsC₂H₅(C₆H₅)2)2(C₆H₄N)2Cl₂}⁽¹⁺⁾*ClO₄^(1-)={Rh(AsC₂H₅(C₆H₅)2)2(C₆H₄N)2Cl₂}ClO₄