Silyl, triethyl-

Base Information

• Chemical Name: Silyl, triethyl-
• CAS No.: 24669-77-0
• Molecular Formula: C6H15Si
• Molecular Weight: 115.271
• Mol file: 24669-77-0.mol

Synonyms:

Chemical Property of Silyl, triethyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silyl, triethyl-

There total 4 articles about Silyl, triethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

C22H34GeHfSi2 + [(benzene)triethylsilyl][tetrakis(pentafluorophenyl)borate] → triethylsilane radical (24669-77-0) + C22H34GeHfSi2(1+)*C24BF20(1-)

Guidance literature:

In benzene; at 20 ℃; for 0.5h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/jacs.8b09214

Reference yield:

triethylsilane (617-86-7) + neophyl radical (25087-41-6) → tert-butylbenzene (253185-03-4,253185-04-5) + 1-phenyl-2-methylpropane (538-93-2) + triethylsilane radical (24669-77-0)

Guidance literature:

In octane; at 120 ℃; Rate constant;

DOI:10.1021/jo00363a010

Reference yield:

triethylsilane (617-86-7) + neophyl radical (25087-41-6) → tert-butylbenzene (253185-03-4,253185-04-5) + triethylsilane radical (24669-77-0)

Guidance literature:

In various solvent(s); at 24.9 ℃; Rate constant; Thermodynamic data; Mechanism; also with Et₃SiD; E_a;

DOI:10.1021/jo00053a046

upstream raw materials:

triethylsilane

neophyl radical

Et₃SiD

Downstream raw materials:

triethylphenylsilane

triethyl-bromo-silane

triethylsilyl chloride

C₂₀H₂₅O₂Si

Refernces

• 1、 Dong, Zhaowen,Cramer, Hanna H.,Schmidtmann, Marc,Paul, Lucas A.,Siewert, Inke,Müller, Thomas. "Evidence for a Single Electron Shift in a Lewis Acid-Base Reaction". supporting information. p. 15419 - 15424. Retrieved 2018/11/03.