Technology Process of Cyclohexanone, 3-(4-methoxyphenyl)-, (3S)-
There total 17 articles about Cyclohexanone, 3-(4-methoxyphenyl)-, (3S)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
chlorobis(ethylene)rhodium(I) dimer; (S)-(+)-[η6-1-bis(3,5-dimethylphenyl)phosphino-2-(3-diphenylphosphino-2-methylpropenyl)benzene-P]chromium(0) dicarbonyl; potassium hydroxide;
In
1,4-dioxane; water;
at 50 ℃;
for 9h;
enantioselective reaction;
Inert atmosphere;
Schlenk technique;
DOI:10.1021/ja503060e
- Guidance literature:
-
naphthalene-2-boronic acid;
With
chlorobis(ethylene)rhodium(I) dimer; (R)-N-cinnamyl-2-methylpropane-2-sulfinamide;
In
1,4-dioxane;
at 40 ℃;
for 0.5h;
Inert atmosphere;
cyclohexenone;
With
potassium phosphate;
In
1,4-dioxane; water;
at 40 ℃;
optical yield given as %ee;
enantioselective reaction;
Inert atmosphere;
DOI:10.1039/c2ob06723d
- Guidance literature:
-
2-bromonaphthalene;
With
n-butyllithium;
In
diethyl ether; hexane;
at 20 ℃;
for 1h;
With
Trimethyl borate;
In
diethyl ether; hexane;
at -78 - 20 ℃;
for 1.5h;
cyclohexenone;
With
water;
bis(ethylene)rhodium acetylacetonate; (S)-(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine);
In
1,4-dioxane;
at 100 ℃;
for 5h;
DOI:10.1016/S0040-4039(99)01412-4
