trans-6-Dodecene

Base Information

• Chemical Name: trans-6-Dodecene
• CAS No.: 29493-00-3
• Molecular Formula: C12H24
• Molecular Weight: 168.323
• Hs Code.: 2901299090
• DSSTox Substance ID: DTXSID20874003
• Nikkaji Number: J97.398J,J97.399H
• Wikidata: Q81981380
• Mol file: 29493-00-3.mol

Synonyms:trans-6-dodecene;6-Dodecene, (E)-;(E)-dodec-6-ene;(6E)-6-Dodecene;6-DODECENE;(E)-6-Dodecene;29493-00-3;7206-17-9;(E)-Dodece-6-ene;DTXSID20874003;DZGHBGLILAEHOR-VAWYXSNFSA-N

Chemical Property of trans-6-Dodecene

Chemical Property:

• Vapor Pressure: 0.255mmHg at 25°C
• Refractive Index: 1.4335 (589.3 nm 20℃)
• Boiling Point: 212.9℃ (745 Torr)
• Flash Point: 73.7°C
• PSA: 0.00000
• Density: 0.7597 g/cm3 (20℃)
• LogP: 4.70320
• XLogP3: 5.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 168.187800766
• Heavy Atom Count: 12
• Complexity: 80.2

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC=CCCCCC
• Isomeric SMILES: CCCCC/C=C/CCCCC

Technology Process of trans-6-Dodecene

There total 13 articles about trans-6-Dodecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

1-Heptene (592-76-7) + 1-acetoxy-3-butene (1576-84-7) → dodec-6-ene (29493-00-3) + cis-non-3-en-1-yl acetate (13049-88-2)

Guidance literature:

With C₃₅H₄₅N₃O₄Ru; In tetrahydrofuran; at 50 ℃; for 2h; under 18.7519 Torr; stereoselective reaction; Inert atmosphere; Glovebox; Flow reactor;

DOI:10.1002/anie.202106410

Reference yield: 55.4%

9,12-octadecadienoic acid (60-33-3,506-21-8,2197-37-7,2420-42-0,2420-55-5,116745-32-5,26085-09-6,64080-88-2,7049-66-3,949900-18-9,60476-23-5,6144-28-1,67922-65-0,89718-18-3) → 1,18-octadec-9-enedioic acid (4494-16-0) + dodec-6-ene (29493-00-3) + pentadec-9-enoic acid (15451-50-0)

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; at 50 ℃; for 72h; Inert atmosphere;

DOI:10.1246/cl.140471

Reference yield: 15.0%

oct-1-ene (111-66-0,25068-25-1) → dodec-6-ene (29493-00-3) + (E,Z)-tridec-6-ene (24949-38-0) + (E)-7-tetradecene (41446-63-3) + (Z)-7-tetradecene (10374-74-0,41446-63-3,41446-60-0)

Guidance literature:

(PCy₃)[1-(2'-pyridinyl)cyclohexan-1-olate]benzylidene-RuCl; at 60 ℃; for 7h; Further Variations:; Catalysts; Temperatures; Product distribution; Kinetics;

DOI:10.1002/adsc.200600474

upstream raw materials:

1-Heptene

ethyl 4-pentenoate

6-dodecyne

cyclohexanoyl cyanide

Downstream raw materials:

1-(dimethylamino)tridecane

N,N-dimethylaminododecane

(2-ethyl-decyl)-dimethyl-amine

(2-butyl-octyl)-dimethyl-amine