6-Tridecene

Base Information

• Chemical Name: 6-Tridecene
• CAS No.: 24949-38-0
• Molecular Formula: C13H26
• Molecular Weight: 182.349
• Hs Code.: 2901299090
• NSC Number: 68824
• UNII: 548QB57U6U
• DSSTox Substance ID: DTXSID10880931
• Nikkaji Number: J364.008F
• Wikidata: Q27160483
• Mol file: 24949-38-0.mol

Synonyms:cis-6-Tridecene;6-Tridecene;6-Tridecene, (Z)-;(Z)-tridec-6-ene;6-Tridecene, (6Z)-;6508-77-6;(Z)-6-Tridecene;(6Z)-6-Tridecene;6-Tridecene, (Z);UNII-548QB57U6U;548QB57U6U;Z-6-Tridecene;NSC68824;.ZETA.-CIS-TRIDECENE;CHEBI:88594;DTXSID10880931;QHOMPCGOCNNMFK-QBFSEMIESA-N;NSC-68824;Q27160483

Chemical Property of 6-Tridecene

Chemical Property:

• Vapor Pressure: 0.0903mmHg at 25°C
• Melting Point: -27.14°C (estimate)
• Refractive Index: 1.4299 (estimate)
• Boiling Point: 232.3°Cat760mmHg
• Flash Point: 87.2°C
• PSA: 0.00000
• Density: 0.77g/cm³
• LogP: 5.09330
• XLogP3: 6.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 9
• Exact Mass: 182.203450829
• Heavy Atom Count: 13
• Complexity: 103

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCC=CCCCCC
• Isomeric SMILES: CCCCCC/C=C\CCCCC

Technology Process of 6-Tridecene

There total 5 articles about 6-Tridecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

oct-1-ene (111-66-0,25068-25-1) → 3‐decene (19398-37-9) + 4-octene (592-99-4,7642-15-1,14850-23-8) + oct-3-ene (14850-22-7,14919-01-8,138663-42-0,592-98-3) + 2-octene (111-67-1) + (E,Z)-tridec-6-ene (24949-38-0) + dodecene-5 (42714-70-5) + 4-undecene (20810-21-3) + tetradec-7-ene (10374-74-0) + cis,trans-2-nonylene (2216-38-8)

Guidance literature:

With rhenium(VII) oxide on aluminum oxide; In supercritical CO₂; at 35 ℃; for 2h; under 67506.8 Torr; chemoselective reaction; Inert atmosphere; Autoclave;

DOI:10.1039/b815121k

Reference yield: 15.0%

oct-1-ene (111-66-0,25068-25-1) → dodec-6-ene (29493-00-3) + (E,Z)-tridec-6-ene (24949-38-0) + (E)-7-tetradecene (41446-63-3) + (Z)-7-tetradecene (10374-74-0,41446-63-3,41446-60-0)

Guidance literature:

(PCy₃)[1-(2'-pyridinyl)cyclohexan-1-olate]benzylidene-RuCl; at 60 ℃; for 7h; Further Variations:; Catalysts; Temperatures; Product distribution; Kinetics;

DOI:10.1002/adsc.200600474

Reference yield:

oct-1-ene (111-66-0,25068-25-1) → 2-nonene (6434-78-2) + (E,Z)-tridec-6-ene (24949-38-0) + dodecene-5 (42714-70-5) + 4-undecene (20810-21-3) + (E)-7-tetradecene (41446-63-3) + (Z)-7-tetradecene (10374-74-0,41446-63-3,41446-60-0)

Guidance literature:

With tetrachlorobis(μ-ethoxy)tetraethoxyditungsten (2) as catalyst; diethylaluminium chloride; In toluene; benzene; at 20 ℃; for 24h; Heating; metathesis with other catalyst in various reaction conditions;

upstream raw materials:

oct-1-ene