2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-iron(III)

Base Information

• Chemical Name: 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-iron(III)
• CAS No.: 131917-66-3
• Molecular Formula: C44Br8 Cl F20 Fe N4
• Molecular Weight: 1697.011544
• Mol file: 131917-66-3.mol

Synonyms:Iron,chloro[2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-5-12)-; 21H,23H-Porphine,2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)-, ironcomplex

Chemical Property of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-iron(III)

Chemical Property:

• PSA: 15.88000
• LogP: 15.84720

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-iron(III)

There total 4 articles about 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-iron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Fe(meso-tetrakis(pentafluorophenyl)-β-octabromoporphyrin) (227202-78-0) → 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-iron(III) chloride (131917-66-3)

Guidance literature:

With hydrogenchloride; In dichloromethane; water;

DOI:10.1021/ja905062w

Reference yield:

5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride (36965-71-6) + bromine (7726-95-6) → meso-tetrakis(pentafluorophenyl)-β-octabromoporphyrinatoiron(III) chloride (131917-66-3)

Guidance literature:

In tetrachloromethane; (N2); Br2 soln. quick addn. to Fe-compd. soln., reflux (18 h, Soret absorption checking), Br2 soln. addn., reflux (several h); cooling, filtration, washing (water), evapn. to dryness, chromy. (neutral alumina, CHCl3), green band collection, treatment with HCl, evapn. to dryness, drying (vac., 110°C);

DOI:10.1006/jcat.1995.1188

Reference yield:

2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrine (139944-26-6) + iron(II) acetate (1834-30-6,2140-52-5,3094-87-9) → 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato-iron(III) chloride (131917-66-3)

Guidance literature:

In acetic acid; pptn. (brine), drying, washing (hexane);

DOI:10.1021/ic00118a010

upstream raw materials:

2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrine

iron(II) acetate

Fe(meso-tetrakis(pentafluorophenyl)-β-octabromoporphyrin)

5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride

Downstream raw materials:

(2,3,7,8,12,13,17,18-octa-β-bromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(II)bis(pyridine)

(2,3,7,8,12,13,17,18-octa-β-bromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(II)(Cl)(1-)

meso-tetrakis(pentafluorophenyl)-β-octabromoporphyrinatoiron(III) azide

[Fe(2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)(NO)]

Refernces

• 1、 Birnbaum, Eva R.,Hodge, Julia A.,Grinstaff, Mark W.,Schaefer, William P.,Henling, Lawrence,et al.. "(19)F NMR Spectra and Structure of Halogenated Porphyrins". . p. 3625 - 3632. Retrieved 2008/10/08.