Iodonium, bis(4-chlorophenyl)-, bromide

Base Information

• Chemical Name: Iodonium, bis(4-chlorophenyl)-, bromide
• CAS No.: 26018-88-2
• Molecular Formula: C12H8Cl2I.Br
• Molecular Weight: 429.91
• DSSTox Substance ID: DTXSID80460385
• Mol file: 26018-88-2.mol

Synonyms:26018-88-2;Iodonium, bis(4-chlorophenyl)-, bromide;Di-4-chlorophenyl iodonium bromide;SCHEMBL11745160;DTXSID80460385;bis(4-chlorophenyl)iodanium;bromide;Iodonium, bis(4-chlorophenyl)-, bromide (1:1)

Chemical Property of Iodonium, bis(4-chlorophenyl)-, bromide

Chemical Property:

• PSA: 0.00000
• LogP: -1.87420
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 427.82312
• Heavy Atom Count: 16
• Complexity: 162

Purity/Quality:

99% ^*data from raw suppliers

Di-4-chlorophenyl iodonium bromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC(=CC=C1Cl)[I+]C2=CC=C(C=C2)Cl.[Br-]

Technology Process of Iodonium, bis(4-chlorophenyl)-, bromide

There total 6 articles about Iodonium, bis(4-chlorophenyl)-, bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

acetic anhydride (108-24-7) + chlorobenzene (108-90-7) → bis(4-chlorophenyl)iodonium bromide (26018-88-2)

Guidance literature:

acetic anhydride; chlorobenzene; With sodium periodate; iodine; In sulfuric acid; at 20 ℃; for 20h;

With potassium bromide; In sulfuric acid; water; for 1h;

DOI:10.1039/c5cc04944j

Reference yield: 40.0%

chlorobenzene (108-90-7) → bis(4-chlorophenyl)iodonium bromide (26018-88-2)

Guidance literature:

chlorobenzene; With Oxone; sulfuric acid; iodine; In water; acetonitrile; at 20 ℃;

With potassium bromide; In water; acetonitrile;

DOI:10.3762/bjoc.14.70

Reference yield:

1-Chloro-4-iodobenzene (637-87-6) → bis(4-chlorophenyl)iodonium bromide (26018-88-2)

Guidance literature:

1-Chloro-4-iodobenzene; With sulfuric acid; at 50 - 55 ℃;

With sodium periodate; at 50 - 55 ℃; for 3h;

With potassium bromide; In water;

DOI:10.1039/c1ob05333g

upstream raw materials:

bromochlorobenzene

4-chloro(dichloroiodo)benzene

chlorobenzene

1-Chloro-4-iodobenzene

Downstream raw materials:

bis(p-chlorophenyl) diselenide

iodobenzene

4,4'-dichlorobiphenyl

4,4'-dichlorodiphenyl sulphone