α-methallyldiphenylmethylsilane

Base Information

• Chemical Name: α-methallyldiphenylmethylsilane
• CAS No.: 108733-51-3
• Molecular Formula: C₁₇H₂₀Si
• Molecular Weight: 252.431
• Mol file: 108733-51-3.mol

Synonyms:

Chemical Property of α-methallyldiphenylmethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-methallyldiphenylmethylsilane

There total 3 articles about α-methallyldiphenylmethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyldiphenylsilane (776-76-1) + crotylmagnesium bromide (36306-56-6) → (Z)-but-2-en-1-yl(methyl)diphenylsilane (91034-75-2) + (E)-but-2-en-1-yl(methyl)diphenylsilane (91034-74-1) + α-methallyldiphenylmethylsilane (108733-51-3)

Guidance literature:

bis(triphenylphosphine)nickel(II) chloride; In diethyl ether; for 16h; Product distribution; Ambient temperature; other catalysts;

DOI:10.1016/S0040-4039(01)80196-9

Reference yield:

allyldiphenyl(methyl)silane (17922-43-9) + methyl iodide (74-88-4) → α-methallyldiphenylmethylsilane (108733-51-3) + ((E)-But-1-enyl)-methyl-diphenyl-silane

Guidance literature:

Yield given. Multistep reaction. Yields of byproduct given;

DOI:10.1246/bcsj.59.2471

Reference yield:

trans-but-2-enyl chloride (4894-61-5) + C26H26CuSi2(1-)*CLiN*Li(1+) → α-methallyldiphenylmethylsilane (108733-51-3)

Guidance literature:

DOI:10.1016/S0040-4039(00)00902-3

upstream raw materials:

methyldiphenylsilane

crotylmagnesium bromide

allyldiphenyl(methyl)silane

methyl iodide