Benzyl-di-t-butylphosphine

Base Information

Chemical Name:Benzyl-di-t-butylphosphine
CAS No.:27286-19-7
Molecular Formula:C15H25P
Molecular Weight:236.337
Hs Code.:
DSSTox Substance ID:DTXSID80457477
Nikkaji Number:J1.432.711H
Wikidata:Q82280326

Synonyms:Benzyl-di-t-butylphosphine;di-tert-butylbenzylphosphine;Benzyldi-tert-butylphosphine;Benzyl-di-tert-butylphosphine;27286-19-7;SCHEMBL706086;benzyl-di-tert-butyl-phosphane;DTXSID80457477;LIDMEVMARAKSDE-UHFFFAOYSA-N;ditertiarybutylphosphinomethylbenzene

Suppliers and Price of Benzyl-di-t-butylphosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzyl-di-t-butylphosphine

Chemical Property:

Boiling Point:56-59 °C(Press: 0.1 Torr)
PSA：13.59000
LogP:5.26550
XLogP3:3.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:236.169387795
Heavy Atom Count:16
Complexity:187

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)P(CC1=CC=CC=C1)C(C)(C)C

Technology Process of Benzyl-di-t-butylphosphine

There total 4 articles about Benzyl-di-t-butylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 13716-10-4
di(tert-butyl)chlorophosphine

: 6921-34-2
benzylmagnesium chloride

: 27286-19-7
benzyl(di-tert-butyl)phosphane

Guidance literature:: di(tert-butyl)chlorophosphine; benzylmagnesium chloride; In tetrahydrofuran; for 48h; Heating / reflux;

With water; ammonium chloride; In tetrahydrofuran; at 20 ℃;

Reference yield: 81.0%

: 13716-10-4
di(tert-butyl)chlorophosphine

: 100-39-0
benzyl bromide

: 27286-19-7
benzyl(di-tert-butyl)phosphane

Guidance literature:: di(tert-butyl)chlorophosphine; benzyl bromide; In acetonitrile; at 100 ℃; for 15h; Inert atmosphere;

With magnesium; In acetonitrile; at 0 - 20 ℃; for 4h; Inert atmosphere;
DOI:10.1021/acs.organomet.5b00671