Tributyl(methoxymethyl)stannane

Base Information

• Chemical Name: Tributyl(methoxymethyl)stannane
• CAS No.: 27490-32-0
• Molecular Formula: C14H32OSn
• Molecular Weight: 335.117
• European Community (EC) Number: 846-289-4
• DSSTox Substance ID: DTXSID60454828
• Mol file: 27490-32-0.mol

Synonyms:tributyl(methoxymethyl)stannane;27490-32-0;Stannane, tributyl(methoxymethyl)-;MFCD28505600;Tributyl-methoxymethyl-tin;tributyl(methoxymethyl) tin;methoxymethyltributyl-stannane;SCHEMBL510037;tributyl methoxymethyl stannane;Tributyl-methoxymethyl-stannane;Tri butyl-methoxymethyl-stannane;DTXSID60454828;UOHDZXTWPSGQLO-UHFFFAOYSA-N;AMY18469;CBA49032;SY250897;A50076;EN300-254359

Chemical Property of Tributyl(methoxymethyl)stannane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 11
• Exact Mass: 336.147518
• Heavy Atom Count: 16
• Complexity: 126

Purity/Quality:

99.3% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)COC

Technology Process of Tributyl(methoxymethyl)stannane

There total 7 articles about Tributyl(methoxymethyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

potassium tert-butylate (865-47-4) + tri-n-butylstannylmethyl iodide (66222-29-5) → tributyl(methoxymethyl)stannane (27490-32-0)

Guidance literature:

With CH₃OH; In tetrahydrofuran; to a soln. of KO-t-Bu in THF was added CH3OH and Bu3SnCH2I, stirring at 50°C for 12h, nitrogen or argon atmosphere;

DOI:10.1021/om00109a002

Reference yield: 86.0%

tri-n-butyl-tin hydride (688-73-3) + chloromethyl methyl ether (107-30-2) → tributyl(methoxymethyl)stannane (27490-32-0)

Guidance literature:

tri-n-butyl-tin hydride; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 - 0 ℃; for 0.5h;

chloromethyl methyl ether; In tetrahydrofuran; hexane; at -78 - 0 ℃;

Reference yield: 86.0%

chloromethyl methyl ether (107-30-2) → tributyl(methoxymethyl)stannane (27490-32-0)

Guidance literature:

With n-butyllithium; tri-n-butyl-tin hydride; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

tri-n-butyl-tin hydride; In tetrahydrofuran; hexane; at -78 - 0 ℃; for 0.5h;

chloromethyl methyl ether; With water; more than 3 stages;

upstream raw materials:

chloromethyl methyl ether

potassium tert-butylate

tri-n-butylstannylmethyl iodide

chloromethoxymethyltributyltin

Downstream raw materials:

4-chlorobenzyl methyl ether

benzyl methyl ether

1-methoxy-4-(methoxymethyl)benzene

1-Methoxymethyl-cyclohex-2-enol