Benzyl methyl ether

Base Information

• Chemical Name: Benzyl methyl ether
• CAS No.: 538-86-3
• Molecular Formula: C8H10O
• Molecular Weight: 122.167
• Hs Code.: 29093090
• European Community (EC) Number: 208-705-7
• NSC Number: 8058
• UNII: F22RLS78BD
• DSSTox Substance ID: DTXSID5060227
• Nikkaji Number: J45.676D
• Wikidata: Q27277530
• Mol file: 538-86-3.mol

Synonyms:benzyl methyl ether;methoxymethylbenzene

Chemical Property of Benzyl methyl ether

Chemical Property:

• Appearance/Colour: Clear colourless to slightly yellowish liquid
• Vapor Pressure: 1.65mmHg at 25°C
• Melting Point: -52.6 °C
• Refractive Index: n20/D 1.502(lit.)
• Boiling Point: 174 °C at 760 mmHg
• Flash Point: 36.4 °C
• PSA: 9.23000
• Density: 0.949 g/cm³
• LogP: 1.83300
• Storage Temp.: Flammables area
• Water Solubility.: practically insoluble
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 122.073164938
• Heavy Atom Count: 9
• Complexity: 65

Purity/Quality:

99% ^*data from raw suppliers

Benzyl Methyl Ether >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R10:
• Hazard Codes: R10:
• Statements: 10
• Safety Statements: 16

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCC1=CC=CC=C1
• Uses: Benzyl methyl ether is used to produce benzaldehyde. It is used as perfuming agents.

Technology Process of Benzyl methyl ether

There total 241 articles about Benzyl methyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

6,7-diazatricyclo<3.2.2.02,4>nona-6,8-diene N-oxide (55563-80-9) → benzyl methyl ether (538-86-3) + benzyl chloride (100-44-7)

Guidance literature:

With hydrogenchloride; In methanol; Mechanism; Ambient temperature;

Reference yield: 75.0%

methanol (67-56-1) + C13H18ClNO3 (135765-55-8) → benzyl methyl ether (538-86-3) + 3-nitroso-3-methylbutanoic acid methyl ester (49680-44-6) + benzyl chloride (100-44-7) + C14H21NO4 (82004-61-3,82004-62-4,90691-23-9)

Guidance literature:

With triethylamine; 1.) -20 deg C, 6 h, 2.) 20 deg C, 1 h;

DOI:10.1007/BF00961356

Reference yield: 70.0%

methanol (67-56-1) + benzyltrimethylsilane (770-09-2) → benzyl methyl ether (538-86-3) + Trimethylmethoxysilane (1825-61-2)

Guidance literature:

With copper(II) bis(tetrafluoroborate); In acetonitrile; for 10h; Irradiation;

DOI:10.1246/cl.1988.229

upstream raw materials:

benzoic acid methyl ester

Dimethoxymethane

phenylmagnesium iodide

bromethyl methyl ether

Downstream raw materials:

(α-methoxy-benzyl)-succinic acid-anhydride

1-Phenylethanol

N-(phenylmethyl)acetamide

benzyl chloride

Refernces

• 1、 Zajak,Byrne. "". . p. 384. Retrieved 1973.
• 2、 Brown,Barton. "". . p. 434. Retrieved 1974.
• 3、 Crotti, Paolo,Renzi, Gabriele,Roselli, Graziella,Di Bussolo, Valeria,Giuli, Sandra,Tsitsigia, Sofia,Romano, Maria Rosaria. "Regiochemical control of the ring-opening of aziridines by means of chelating processes. Part 4: Regioselectivity of the opening reactions with MeOH of 1-(benzyloxy)-2,3- and -3,4-N-(methoxycarbonyl)aziridoalkanes under condensed and gas-phase operating conditions". . p. 5501 - 5509. Retrieved 2007.
• 4、 Carlet, Federica,Bertarini, Greta,Broggini, Gianluigi,Pradal, Alexandre,Poli, Giovanni. "Oxoammonium-Mediated Allylsilane–Ether Coupling Reaction". supporting information. p. 2162 - 2168. Retrieved 2021/04/02.
• 5、 He, Lei,Li, Wen-Cui,Lu, An-Hui,Wang, Qing-Nan,Weng, Xue-Fei,Zhou, Bai-Chuan. "Regulating Aromatic Alcohols Distributions by Cofeeding Methanol with Ethanol over Cobalt-Hydroxyapatite Catalyst". . . Retrieved 2020/03/24.