Ni(P(C₆H₁₁)3)(N(C₆H₅)C(O)CH₂CH(CH₂)2CHCH₂)

Base Information

• Chemical Name: Ni(P(C₆H₁₁)3)(N(C₆H₅)C(O)CH₂CH(CH₂)2CHCH₂)
• CAS No.: 114572-12-2
• Molecular Formula: C₃₁H₄₈NNiOP
• Molecular Weight: 540.392
• Mol file: 114572-12-2.mol

Synonyms:

Chemical Property of Ni(P(C₆H₁₁)3)(N(C₆H₅)C(O)CH₂CH(CH₂)2CHCH₂)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(P(C₆H₁₁)3)(N(C₆H₅)C(O)CH₂CH(CH₂)2CHCH₂)

There total 2 articles about Ni(P(C₆H₁₁)3)(N(C₆H₅)C(O)CH₂CH(CH₂)2CHCH₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tricyclohexylphosphine(1,5-hexadiene)nickel (74945-90-7) + phenyl isocyanate (103-71-9) → Ni(P(C6H11)3)(N(C6H5)C(O)CH2CH(CH2)2CHCH2) (114572-12-2) + Ni(P(C6H11)3)(N(C6H5)C(O)CH((CH2)2CHCH2)CH2) (114572-13-3)

Guidance literature:

In diethyl ether; to a suspn. of Ni-complex in diethyl ether phenylisocyanate is added at-78°C, mixt. is allowed to warm to -10°C with stirring (without air); after 2 days the solid is filtered off, washed with diethyl ether and dried; mixt of regioisomers, total yield 60%;

DOI:10.1016/0022-328X(87)80256-5

Reference yield:

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 1,5-Hexadien (592-42-7) + phenyl isocyanate (103-71-9) + tricyclohexylphosphine (2622-14-2) → Ni(P(C6H11)3)(N(C6H5)C(O)CH2CH(CH2)2CHCH2) (114572-12-2) + Ni(P(C6H11)3)(N(C6H5)C(O)CH((CH2)2CHCH2)CH2) (114572-13-3)

Guidance literature:

In diethyl ether; a suspn. of Ni-complex, phosphine, phenylisocyanate and 1,5-hexadiene in diethyl ether is prepd. at -78°C, mixt. is allowed to warm to -10°C over 20 h with stirring (without air); after 2 days the solid is filtered off, washed with diethyl ether and dried; mixt. of regioisomers, total yield 64%; elem. anal.;

DOI:10.1016/0022-328X(87)80256-5

Reference yield:

[2,2]bipyridinyl (366-18-7) + Ni(P(C6H11)3)(N(C6H5)C(O)CH2CH(CH2)2CHCH2) (114572-12-2) + tricyclohexylphosphine(1,5-hexadiene)nickel (74945-90-7) → ((C5H4N)2)NiN(C6H5)C(O)CH2CH(CH2CH2CHCH2) (114571-96-9) + ((C5H4N)2)Ni(N(C6H5)C(O)CH(CH2CH2CHCH2)CH2)

Guidance literature:

In tetrahydrofuran; to a soln. of Ni-compd. (mixt. of regioisomers) 2,2'-bipyridine is added at -40°C, warming to 20°C for 12 h (without air); concn., addn. of diethyl ether, filtration, washing with diethyl ether,drying, elem. anal. (mixt. of regioisomers);

DOI:10.1016/0022-328X(87)80256-5

upstream raw materials:

tricyclohexylphosphine(1,5-hexadiene)nickel

phenyl isocyanate

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

1,5-Hexadien

Downstream raw materials:

((C₅H₄N)2)NiN(C₆H₅)C(O)CH₂CH(CH₂CH₂CHCH₂)