2,3,3a,5,6,7a-Hexahydro-2,5-methano-1H-inden-7(4H)-one

Base Information

• Chemical Name: 2,3,3a,5,6,7a-Hexahydro-2,5-methano-1H-inden-7(4H)-one
• CAS No.: 27567-85-7
• Molecular Formula: C10H14O
• Molecular Weight: 150.221
• Hs Code.: 2914299000
• Mol file: 27567-85-7.mol

Synonyms:protoadamantan-7-one;4-Protoadamantanone;4-Protoadamantanon;4-protoadanantanone;protoadamantan-4-one;tricyclo[4.3.1.0~3,8~]decan-4-one;tricyclo[4.3.1.03,8]decane-4-one;1,2,3,5,6,7-Hexahydro-2,6-methaninden-4-one;2,5-Methanoindan-7(4H)-one,tetrahydro;

Chemical Property of 2,3,3a,5,6,7a-Hexahydro-2,5-methano-1H-inden-7(4H)-one

Chemical Property:

• PSA: 17.07000
• LogP: 2.01160

Purity/Quality:

99% ^*data from raw suppliers

tricyclo[4.3.1.0^{3,8}]decan-4-one ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,3,3a,5,6,7a-Hexahydro-2,5-methano-1H-inden-7(4H)-one

There total 3 articles about 2,3,3a,5,6,7a-Hexahydro-2,5-methano-1H-inden-7(4H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

adamantane (281-23-2) → 1-adamanthanol (768-95-6) + 1-adamantanol (700-57-2) + 4-protoadamantanone (27567-85-7)

Guidance literature:

With potassium permanganate; borontrifluoride acetic acid; In acetonitrile; at 23 ℃; for 0.166667h;

DOI:10.1039/DT9950000695

Reference yield:

polymer, synthesized by cationic ring-opening polymerization, Mn = 10600, Mw/Mn = 1.44; monomer(s): 4,6-dioxatetracyclo[6.3.1.1.3,1003,7]tridecane-5-thione → 2-Adamantanone (700-58-3) + carbon oxide sulfide (463-58-1) + 4-protoadamantanone (27567-85-7)

Guidance literature:

at 400 ℃; for 0.00138889h; Further Variations:; Temperatures; Product distribution;

DOI:10.1021/ma012094i

Reference yield:

adamantane (281-23-2) → 2-Adamantanone (700-58-3) + 1-adamanthanol (768-95-6) + 4-protoadamantanone (27567-85-7) + 1-hydroxy-2-adamantanone (26921-51-7)

Guidance literature:

With C₉₆H₉₆Fe₂N₁₆O; tetrabutylammonium oxone; In dichloromethane; at 20 ℃; for 0.166667h;

DOI:10.1016/j.tetlet.2010.10.023

upstream raw materials:

adamantane

Downstream raw materials:

1,2-dibromoadamantane

2-bromo-1-adamantanol

2-bromo-1-adamantyl acetate

1--2-adamantyl-formiat