(E)-Stilbene-2-amine

Base Information

• Chemical Name: (E)-Stilbene-2-amine
• CAS No.: 27652-35-3
• Molecular Formula: C14H13N
• Molecular Weight: 195.264
• Mol file: 27652-35-3.mol

Synonyms:(E)-2-(2-phenylethenyl)phenylamine;trans-ortho-aminostilbene;Benzenamine, 2-(2-phenylethenyl)-, (E)-;2-aminostilbene;aminostilbene;(E)-2‐styrylaniline;2-[(E)-2-phenylethenyl]aniline;

Chemical Property of (E)-Stilbene-2-amine

Chemical Property:

• PSA: 26.02000
• LogP: 4.02040

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-Stilbene-2-amine

There total 33 articles about (E)-Stilbene-2-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 2-bromoaniline (615-36-1) → (E)-2-styrylaniline (27652-35-3)

Guidance literature:

With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine; at 125 ℃;

DOI:10.1016/j.tet.2016.06.063

Reference yield: 99.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 2-iodophenylamine (615-43-0) → (E)-2-styrylaniline (27652-35-3)

Guidance literature:

With tributyl-amine; In N,N-dimethyl-formamide; at 120 ℃;

DOI:10.1055/s-2008-1072579

Reference yield: 98.0%

trans-2-phenylvinylboronic acid (6783-05-7) + 2-bromoaniline (615-36-1) → (E)-2-styrylaniline (27652-35-3)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; water; toluene; for 24h; Reflux;

DOI:10.1002/anie.200800689

upstream raw materials:

quinoline

(Z)-2-aminostilbene

styrene

2-bromoaniline

Downstream raw materials:

indole-2-carboxylic acid methyl ester

2-hydroxyquinoline

(Z)-2-aminostilbene

2-(2-phenylethyl)aniline