SODIUM-8-OXYQUINOLATE

Base Information

• Chemical Name: SODIUM-8-OXYQUINOLATE
• CAS No.: 2872-54-0
• Molecular Formula: C9H7NO.Na
• Molecular Weight: 167.143
• Hs Code.: 2933499090
• Mol file: 2872-54-0.mol

Synonyms:SODIUM-8-OXYQUINOLATE;

Chemical Property of SODIUM-8-OXYQUINOLATE

Chemical Property:

• PSA: 35.95000
• LogP: 2.37860

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of SODIUM-8-OXYQUINOLATE

There total 2 articles about SODIUM-8-OXYQUINOLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

8-quinolinol (148-24-3,24804-14-6) → sodium 8-quinolinolate (2872-54-0)

Guidance literature:

With sodium; In acetonitrile; for 0.416667h;

Reference yield:

8-hydroxyquinoline-OD (100651-83-0) → sodium 8-quinolinolate (2872-54-0) + deuterium hydride

Guidance literature:

With sodium hydride; In 1,4-dioxane; Mechanism;

DOI:10.1039/c9gc02824b

Reference yield: 96.0%

sodium 8-quinolinolate (2872-54-0) + diiodo(phenyl)bismuth(III) (39110-03-7) → [NaBiPh(8-quinolinolato)3]

Guidance literature:

In ethanol; N2-atmosphere; addn. of soln. of Na-salt to soln. of PhBiI2 (pptn.); stirring (17 h), volume reduction, filtration, washing (EtOH, light petroleum), drying; elem. anal.;

DOI:10.1071/ch9960231

upstream raw materials:

8-quinolinol

8-hydroxyquinoline-OD

Downstream raw materials:

quinolin-8-yl bis(p-nitrophenyl) phosphate

8-(picryloxy)quinoline

{Rh(η4-1,5-cyclooctadiene)(μ-8-hydroxyquinolate)}

[Ir(8OQ)(cod)]

Refernces

• 1、 Varshavsky,Galding,Khrustalev,Podkorytov,Smirnov,Gindin,Nikolskii. "Rhodium(I) dimethyl sulfoxide oxyquinolinato carbonyl complex, [Rh(Oxq)(CO)(DMSO)]. NMR and X-ray structure data". . p. 123 - 126. Retrieved 2014.
• 2、 Al-Noor, Taghreed H.,Karam, Nisreen H.,H. Ghanim, Faeza,Kindeel, Alia S.,Al-Dujaili, Ammar H.. "Synthesis, characterization and liquid crystalline properties of novel benzimidazol-8-hydroxyquinoline complexes". . p. 612 - 617. Retrieved 2017.