cycloocta-1,5-diene; quinolin-8-ol; rhodium

Base Information

Chemical Name:cycloocta-1,5-diene; quinolin-8-ol; rhodium
CAS No.:33409-86-8
Molecular Formula:C₁₇H₁₈IrNO
Molecular Weight:444.556
Hs Code.:

Synonyms:

Suppliers and Price of cycloocta-1,5-diene; quinolin-8-ol; rhodium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 5 raw suppliers

Chemical Property of cycloocta-1,5-diene; quinolin-8-ol; rhodium

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of cycloocta-1,5-diene; quinolin-8-ol; rhodium

There total 5 articles about cycloocta-1,5-diene; quinolin-8-ol; rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: chloro(1,5-cyclooctadiene)iridium(I) dimer

: 2872-54-0
sodium 8-quinolinolate

: 33409-86-8
[Ir(8OQ)(cod)]

Guidance literature:: In tetrahydrofuran; N2-atmosphere, stirring (room temp., 2.5 h), evapn. to dryness, extn. (THF), filtration (column of diatomaceous earth); crystn. on addn. of CH3CN, filtration, drying (vac., overnight);

Reference yield: 63.0%

: 148-24-3,24804-14-6
8-quinolinol

: 12148-71-9
(1,5-cyclooctadiene)(methoxy)iridium(l) dimer

: 33409-86-8
[Ir(8OQ)(cod)]

Guidance literature:: In dichloromethane; at 20 ℃;
DOI:10.1007/s10870-014-0495-5

Reference yield: 62.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 14104-20-2
silver tetrafluoroborate

: 2872-54-0
sodium 8-quinolinolate

: 33409-86-8
{Rh(η4-1,5-cyclooctadiene)(μ-8-hydroxyquinolate)}

Guidance literature:: In acetonitrile; benzene; byproducts: AgCl, NaBF4; stirring (15 min), sepn. of AgCl (filtration off), addn. of ligand, stirring (overnight), evapn. of soln. to dryness, extn. (benzene), sepn. of NaBF4 (filtration off); removal of solvent, recrystn. (CH2Cl2/CH3CN);