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Basic Information
CAS No.: 12071-83-9
Name: Propineb
Molecular Structure:
Molecular Structure of 12071-83-9 (Propineb)
Formula: C5H8N2S4Zn
Molecular Weight: 289.786
Synonyms: Zinc,[[(1-methyl-1,2-ethanediyl)bis[carbamodithioato]](2-)]-;Zinc, [[2-[(dithiocarboxy)amino]-1-methylethyl]carbamodithioato(2-)-kS,kS']- (9CI);Zinc, [propylenebis[dithiocarbamato]]-(7CI,8CI);Carbamodithioic acid, (1-methyl-1,2-ethanediyl)bis-, zinc complex;Antracol;Antracol 70;Antracol NM;B 5078;Bayer 46131;Carbamodithioic acid,(1-methyl-1,2-ethanediyl)bis-, zinc salt;Cypromate;Methylzineb;Mezineb;
EINECS: 235-134-0
Melting Point: 160oC
Boiling Point: 315.4oC at 760 mmHg
Flash Point: 144.5oC
Appearance: Off-White to Light Beige Solid
Hazard Symbols: N
Risk Codes: 51/53
Safety: 60-61
Transport Information: UN3077 9/PG 3
PSA: 165.84000
LogP: 1.76530
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Chemistry

IUPAC Name: Zinc N-[1-(sulfidocarbothioylamino)propan-2-yl]carbamodithioate
CAS: 12071-83-9
Molecular Formula: C5H8N2S4Zn 
Molecular Weight: 289.80
Molecular structure:
EINECS: 235-134-0
ACD/LogD (pH 5.5): -2.75 
ACD/LogD (pH 7.4): -2.75 
ACD/BCF (pH 5.5): 1 
ACD/BCF (pH 7.4): 1 
ACD/KOC (pH 5.5): 1 
ACD/KOC (pH 7.4): 1 
H bond acceptors: 2 
H bond donors: 2 
Freely Rotating Bonds: 3 
Flash Point: 144.5 °C 
Enthalpy of Vaporization: 55.66 kJ/mol 
Boiling Point: 315.4 °C at 760 mmHg 
Vapour Pressure: 0.000439 mmHg at 25°C
Classification Code: Agricultural Chemical; Fungicide, bactericide, wood preservative; Mutation data; Reproductive Effect

Uses

 Propineb (CAS No.12071-83-9) is commonly used as agricultural fungicide.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
quail LD50 unreported > 5gm/kg (5000mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C252, 1991.
rabbit LD50 oral 2500mg/kg (2500mg/kg)   "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R., Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971Vol. -, Pg. 123, 1971.
rat LC50 inhalation > 693mg/m3/4H (693mg/m3)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A348, Pg. 1983,
rat LD50 oral 8500mg/kg (8500mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A348, Pg. 1983,
rat LD50 skin > 1gm/kg (1000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A348, Pg. 1983,

RTECS:  ZH4950000

Safety Profile

Hazard Codes:  N
Risk Statements:  51/53 (R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.)
Safety Statements:  60-61 (S60:This material and its container must be disposed of as hazardous waste. S61:Avoid release to the environment. Refer to special instructions / safety data sheets.)
RIDADR:  UN3077 9/PG 3
When Propineb (CAS No.12071-83-9) gets burnt may produce toxic gases such as sulfur oxides and nitrogen oxides.

Specification

  Propineb , its CAS register number is 12071-83-9, it's also named as Airone ; Bay46131 ; Bayer46131 ; Lh30/z ; Lh3012 ; Propylenebis(dithiocarbamato)zinc ; Taifen ; Propinebe ; Zipromat ; Mezineb ,and so on.