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Prussian Blue

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Name

Prussian Blue

EINECS 237-875-5
CAS No. 14038-43-8 Density 1.8 g/cm3
PSA 428.22000 LogP 0.28454
Solubility practically insoluble in water Melting Point N/A
Formula 4Fe(CN)6.3Fe Boiling Point 25.7oC at 760 mmHg
Molecular Weight 859.248 Flash Point N/A
Transport Information N/A Appearance dark blue crystalline powder
Safety 22-24/25 Risk Codes R40; R22; R10; R36/38; R23/25; R11; R36/37/38
Molecular Structure Molecular Structure of 14038-43-8 (Prussian Blue) Hazard Symbols Xn,T,F,Xi
Synonyms

Ferrate(4-),hexacyano-, iron(3+) (3:4) (8CI);Ferrate(4-), hexakis(cyano-C)-, iron(3+)(3:4), (OC-6-11)-;Antidotum-Thallii-Heyl;Ferrate(1-), hexakis(cyano-C)di-;Ferric ferrocyanide (Fe4[Fe(CN)6]3);Ferrihexacyanoferrate;Ferrocin;Iron ferrocyanide;Iron(3+) hexacyanoferrate(4-) (4:3);Iron(III) ferrocyanide;Tetrairon tris(hexacyanoferrate(4-));Tetrairontris(hexacyanoferrate);

Article Data 58

Prussian Blue Consensus Reports

Cyanide and its compounds are on the Community Right-To-Know List.

Prussian Blue Standards and Recommendations

OSHA PEL: TWA 5 mg(CN)/m3
ACGIH TLV: CL 5 mg(CN)/m3 (skin)
DFG MAK: 5 mg/m3
NIOSH REL: (Cyanide) CL 5 mg(CN)/m3/10M

Prussian Blue Specification

The Prussian Blue is an organic compound with the formula 4Fe(CN)6.3Fe. The IUPAC name of this chemical is iron(2+); iron(3+); octadecacyanide. With the CAS registry number 14038-43-8, it is also named as Tetrairon(3+) tris[hexacyanoferrate(4-)]. The product's categories are Dyes and Pigments; Inorganics. Besides, it is a dark blue crystalline powder, which should be stored in a ventilated and dry place.

Physical properties about Prussian Blue are: (1)#H bond acceptors: 18; (2)Polar Surface Area: 428.22 Å2.

When you are using this chemical, please be cautious about it as the following:
When you are using it, do not breathe dust and avoid contact with skin and eyes.

You can still convert the following datas into molecular structure:
(1)SMILES: [Fe+3].[Fe+3].[Fe+3].[Fe+3].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N
(2)InChI: InChI=1/18CN.7Fe/c18*1-2;;;;;;;/q;;;;;;;;;;;;;;;;;;3*-4;4*+3/r3C6FeN6.4Fe/c3*8-1-7(2-9,3-10,4-11,5-12)6-13;;;;/q3*-4;4*+3
(3)InChIKey: DNMNDNSFJMUUFM-LNXSYPOOAH
(4)Std. InChI: InChI=1S/18CN.7Fe/c18*1-2;;;;;;;/q;;;;;;;;;;;;;;;;;;3*-4;4*+3
(5)Std. InChIKey: DNMNDNSFJMUUFM-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD oral > 8gm/kg (8000mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(1), Pg. 35, 1991.
mouse LD50 intraperitoneal 2gm/kg (2000mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BLOOD: CHANGES IN SPLEEN
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(1), Pg. 35, 1991.
rabbit LD oral > 8gm/kg (8000mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(1), Pg. 35, 1991.
rat LD oral > 8gm/kg (8000mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(1), Pg. 35, 1991.
rat LD50 intraperitoneal 2100mg/kg (2100mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LIVER: OTHER CHANGES
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(1), Pg. 35, 1991.
rat LDLo intratracheal 250mg/kg (250mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

KIDNEY, URETER, AND BLADDER: OTHER CHANGES
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(1), Pg. 35, 1991.

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