- Rhenium
- Rhenium bromide
- Rhenium bromide (ReBr5)
- Rhenium chloride
- Rhenium fluoride (ReF7)(6CI,7CI,8CI,9CI)
- Rhenium fluoride(ReF6), (OC-6-11)-
- Rhenium oxide
- Rhenium sulfide
- RHENIUM TRICHLORIDE
- Rhenium(IV) chloride
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- 13569-72-7Tantalum chloride(TaCl4)
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| Name |
RHENIUM TRICHLORIDE |
EINECS | 236-987-1 |
| CAS No. | 13569-63-6 | Density | 4800 kg/m3 |
| PSA | 0.00000 | LogP | 2.06850 |
| Solubility | Soluble in water. | Melting Point |
decomposes at 500℃ [LID94] |
| Formula | Cl3Re | Boiling Point | 500 °C (decomposes) |
| Molecular Weight | 292.566 | Flash Point | °C |
| Transport Information | N/A | Appearance | red, crystalline, nonvolatile solid |
| Safety | 26-37/39 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi C
|
| Synonyms |
Rheniumchloride; Rhenium trichloride |
RHENIUM TRICHLORIDE Chemical Properties
IUPAC Name: Trichlororhenium
Synonyms: Rhenium trichloride ; Rhenium(iii) chloride ; Rhenium chloride ; Rhenium(+3)chloride ; Rheniumchloride(recl3) ; Rheniumchloridemeshredblackpowder ; Rhenium(III) chloride, 99.8+% (metals basis) ; Rhenium(III) trichloride
Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhenium Salts;RheniumMetal and Ceramic Science;Salts
CAS NO: 13569-63-6
Molecular Formula: Cl3Re
Molecular Weight: 292.57
Molecular Structure: .png)
EINECS: 236-987-1
Mol File: 13569-63-6.mol
Boiling Point: >550°C
Sensitive: Rhenium trichloride (CAS NO.13569-63-6) is moisture sensitive .
RHENIUM TRICHLORIDE Uses
Rhenium trichloride (CAS NO.13569-63-6) is used as a starting material for synthesis of rhenium complexes. ReCl3 can react with peralkylated benzene-metal complexes that act as electron reservoirs.
RHENIUM TRICHLORIDE Production
Rhenium trichloride (CAS NO.13569-63-6) is most efficiently prepared by the thermal decomposition of rhenium pentachloride in nitrogen. Other methods include reacting sulphuryl chloride with rhenium powder with or without the addition of aluminium chloride, the thermal decomposition of salts of hexachlororhenic(IV) acid, or the heating of Re2(O2CCH3)4Cl2 under HCl gas.
RHENIUM TRICHLORIDE Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| cat | LDLo | intravenous | 20mg/kg (20mg/kg) | VASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION | Journal of Pharmaceutical Sciences. Vol. 57, Pg. 321, 1968. |
| mouse | LD50 | intraperitoneal | 280mg/kg (280mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: EXCITEMENT | Journal of Pharmaceutical Sciences. Vol. 57, Pg. 321, 1968. |
RHENIUM TRICHLORIDE Consensus Reports
Reported in EPA TSCA Inventory.
RHENIUM TRICHLORIDE Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Cl−. See also RHENIUM and CHLORIDES.
Hazard Codes 
Xi
Risk Statements 36/37/38
R36/37/38: Rhenium trichloride (CAS NO.13569-63-6) is irritating to eyes, respiratory system and skin.
Safety Statements 26-37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: When Rhenium trichloride (CAS NO.13569-63-6) is used ,wear suitable gloves and eye/face protection.
WGK Germany 3
RTECS VI0875000
RHENIUM TRICHLORIDE Specification
Rhenium trichloride prepared from rhenium pentachloride without further treatment is chemically reactive, but if it is vacuum sublimed at 500oC, then it becomes comparatively unreactive. However, x-ray diffraction tests show no observable difference in structure between the untreated and vacuum sublimed material.
The heat of oxidation according to the equation,
ReCl3(s) + 4OH- + 2OCl- → ReO4- + 2H2O + 5Cl-
is 190.7 ± 0.2 kcal/mol.
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